Novel multifunctional switchable chemosensors based on fluorescent electrospun (ES) nanofibers with sensitivity toward magnetism, temperature, and mercury ions (Hg2+) were prepared using blends of poly(N-isopropylacrylamide)-co-(N-methylolacrylamide)-co-(Acrylic acid), the fluorescent probe 1-benzoyl-3-[2-(2-allyl-1,3-dioxo-2,3-dihydro-1Hbenzo[de]isoquinolin-6-ylamino)ethyl]-thiourea (BNPTU), a...

We study the form factor of thermoresponsive microgels based on poly(N-isopropylacrylamide) at high generalized volume fractions, ζ, where the particles must shrink or interpenetrate to fit into the available space. Small-angle neutron scattering with contrast matching techniques is used to determine the particle form factor. We find that the particle size is constant up to a volume fraction ro...

Nematic droplets are droplets composed of elongated molecules that tend to point in the same direction but do not have any positional order. Such droplets are well known to adopt a spindle shape called tactoid. How such droplets condensate or melt and how the orientational symmetry is broken remains however unclear. Here we use a colloidal system composed of filamentous viruses as model rod-lik...

PURPOSE To determine the safety and efficacy of poly-N-isopropylacrylamide, a thermoresponsive adhesive, for sutureless sclerotomy closure in rabbits. METHODS Eight rabbits were randomized into three groups: short-term acute, mid-term chronic, and long-term chronic studies. A corresponding control group in which the scleral wounds were sutured by 6-0 vicryl sutures was assigned for each study...

Abstract The tribological behavior of 316L stainless steel/CoCrMo alloy contacts under aqueous lubrication was investigated in this work. Three types microgels including poly(N-isopropylacrylamide) (PNIPAM), polyacrylic acid (PAA), and poly(N-isopropylacrylamide-co-acrylic acid) (PNIPAM-co-PAA) were prepared used as lubricant additives solutions. Tribological tests conducted using a ball-on-dis...

The LCST-transitions of linear, well-defined polymers of N-isopropylacrylamide (NIPAM) and N-vinylcaprolactam (VCL), including a homopolymer mixture, diblock and statistical copolymers, in water are explored and compared by applying turbidity and FTIR measurements in combination with two-dimensional correlation spectroscopy (2Dcos). Only one transition is observed in all polymer systems, sugges...

Several proposals to construct artificial photoresponsive polymer systems have been described. chromophores in the backbone reversibly changed the conformation by ultraviolet light irradiation(410 > > 350 nm), which causes the trans to cis isomerization of the chromophores. Aqueous solutions of poly(N-isopropylacrylamide) with pendant azobenzene chromophores showed a photostimulated phase separ...

A novel nanocomposite hydrogel with controllable multiple thermosensitivity has been synthesized by introducing poly(ethylene glycol) (PEG) into clay/poly(N-isopropylacrylamide) (PNIPAAm) nanocomposite hydrogel, which exhibits double thermosensitive phase transition: a UCST and a LCST spontaneously.

Low polydispersity poly(N-isopropylacrylamide) with a biotin end-group was obtained in one step from a biotinylated initiator for atom transfer radical polymerization and interacted with streptavidin to generate the thermosensitive polymer-protein conjugate.

An interesting transition from spherical micelles to vesicles, which was time and temperature dependent, was observed for the first time; it is tentatively attributed to the thermal hysteresis of temperature-responsive poly(N-isopropylacrylamide).