Although hydrogen cyanide has become quite a common molecular tracing species for a variety of astrophysical sources, it, however, exhibits dramatic non-LTE behaviour in its hyperfine line structure. Individual hyperfine components can be strongly boosted or suppressed. If these so-called hyperfine line anomalies are present in the HCN rotational spectra towards low or high mass cores, this wil...

Interplay of quantum mechanical calculations and experimental data on hyperfine coupling constants of ethyl radical in zeolites at several temperatures was engaged to study the geometries and binding energies and to predict the temperature dependence of hyperfine splitting of a series of alkyl radicals in zeolites for the first time. The main focus is on the hyperfine interaction of alkyl radic...

The Mössbauer spectra of nanoferrite materials such as Ni0.25Mn0.75Fe2O4, Co0.5Mn0.5Fe2O4 and Ni0.4Co0.6Fe2O4 have been reported and the above materials were prepared by sol-gel combustion method using metal nitrates as source material and Polyvinyl alcohol(PVA) as...

electron paramagnetic resonance (epr) spectroscopy, also known as electron spin resonance(esr) especially among physicists, is a strong and versatile spectroscopic method forinvestigation of paramagnetic systems, i.e. systems like free radicals and most transition metalions, which have unpaired electrons. the sensitivity and selectivity of epr are notable andintriguing as compared to other spec...

The one-loop self-energy correction to the hyperfine structure splitting of the 1s and 2s states of hydrogenlike ions is calculated both for the point and finite nucleus. The results of the calculation are combined with other corrections to find the ground state hyperfine splitting in lithiumlike 209 Bi 80+ and 165 Ho 64+. The recent experimental investigation of the ground-state hyperfine spli...

The one-loop self-energy correction to the hyperfine structure splitting of the 1s and 2s states of hydrogenlike ions is calculated both for the point and finite nucleus. The results of the calculation are combined with other corrections to find the ground state hyperfine splitting in lithiumlike 209 Bi 80+ and 165 Ho 64+. The recent experimental investigation of the ground-state hyperfine spli...

We report on the first theoretical investigation of M(F)-dependent lifetimes due to interference between a magnetic octupole transition and a hyperfine induced electric quadrupole transition. Extensive multiconfiguration Dirac-Fock calculations are used to model the hyperfine quenching of the magnetic octupole decay of 3d(9)4s 3D3 and the state mixing between the 3D3 and 3D2 due to hyperfine in...