Azo dye of quinoline named 5-(3-pyridylazo)-8-hydroxyquinoline (PAHQ) was prepared via coupling reaction diazonium salt 3-aminopyridine and 8-hydroxyquinoline. he PAHQ characterized by elemental analysis, mass spectroscopy 1H-NMR. The complexes were under 2:1 (L:M) mole ratio. infrared spectroscopy, UV-Vis, molar conductance, magnetic susceptibility. IR spectra data indicate that ligand is bid...

Abstract A series of novel substituted-azo dyes 8-(aryldiazenyl)quinolin-5-ol (5a-i) were synthesized by the coupling reaction 5-hydroxyquinoline with diazotized aniline derivatives in presence NaNO2 HCl/H2O mixture. The study spectroscopic and solvatochromic properties performed FT-IR, 1H 13C-NMR UV-Visible spectroscopies. tautomerism these was studied using deuteration technique measurements....

Some reactivity in the oxidation of methanol to formaldehyde has been spectroscopically detected on the methanolic mother liquors of a copper(ii) complex of a Schiff base ligand derived from the condensation of 8-hydroxyquinoline-2-carboxaldehyde and 2-tosylaminomethylaniline. An investigation has shown that 2-tosylaminomethylaniline (HA(TS)) plays a dual role in the oxidative process acting as...

Brunescent (dark brown) cataract is particularly prevalent in the tropics. Enzymatic digestion of the insoluble protein fraction of brunescent cataractous eye lenses from India, followed by high performance liquid chromatographic separation of the pigments and spectroscopic investigations, have led to the identification of one of the pigments as 4-hydroxyquinoline-3-[alpha-aminoacetic acid] (co...

Some natural compounds of plants including phenols and alkaloids induce mitosis depressive that are blocked cell division. Field dodder (Cuscuta campestris Yunck.) and eastern dodder (Cuscuta monogyna Vahl.) are the most widespread obligatory parasitic species. In the present study, end of summer 2015, field dodder and eastern dodder are collected from Alhagi maurorum Medik. host and Vine (Viti...

Naturally occurring quinolone and quinolone-like compounds, such as quinine, 2-hydroxyquinoline, 4-hydroxyquinoline, and 2-heptyl-3-hydroxy-4(1H)-quinolone, increased expression of qnrS1 in Escherichia coli 2.3- to 11.2-fold, similar to the synthetic quinolone ciprofloxacin. In contrast, chromosomal qnrVS1 of Vibrio splendidus was not induced by these compounds. Molecules associated with quorum...

Column chelation chromatography on controlled pore glass-8-hydroxyquinoline was demonstrated to be a very efficient method for removing trace metal contaminants from concentrated macronutrient salt solutions used to prepare nutrient media. By using (63)Ni and (65)Zn radio-isotopes as tracers, controlled pore glass-8-hydroxyquinoline column packings were found to retain 99.9% of the radiotracer ...

In this study, the potential of 8-Hydroxyquinoline grafted SBA-15 to extract of Cu2+ cations from aqueous solutions was investigated. SBA-15 nanoporous silica was chemically grafted with 8-Hydroxyquinoline groupsaccording to the procedure in the literature. The presence of organic groups in the silica framework was demonstrated by FTIR spectrum. The grafted product showed th...

Dinuclear rhenium(I) complexes having a fac-[Re(CO)3](+) moiety of general formula fac-[Re2(CO)6(hq)2] have been synthesized in excellent yield by reacting [Re(CO)5Cl] with Hhq in a ratio of 1 : 1 in toluene in an argon atmosphere. Here hq(-) is the deprotonated form of 5-phenylazo-8-hydroxyquinoline (Hhq(1)), 5-(2-naphthylazo)-8-hydroxyquinoline (Hhq(2)) and 5-(2-fluorineazo)-8-hydroxyquinolin...