The structures and mechanical properties of both physically and covalently cross-linked nanocomposite hydrogels made from poly(ethylene glycol) (PEG) and silicate nanoparticles (Laponite RD) are investigated. Injectable nanocomposite precursor solutions can be covalently cross-linked via photopolymerization. The resulting hydrogels are transparent and have interconnected pores, high elongation ...

Unique combinations of hard and soft components found in biological tissues have inspired researchers to design and develop synthetic nanocomposite gels and hydrogels with elastomeric properties. These elastic materials can potentially be used as synthetic mimics for diverse tissue engineering applications. Here we present a set of elastomeric nanocomposite hydrogels made from poly(ethylene gly...

the clay crosslinked hydrogel nanocomposites were synthesized by graft copolymerization of acrylamide and itaconic acid in the presence of different amounts of laponite using ammonium persulfate and n,n,n',n'-tetramethylethylene diamine  )temed) as a free radical initiator and catalyst, respectively. the xrd patterns of nanocomposites showed that the clay layers are completely exfolia...

Polyacrylic acid/ octavinyl polyhedral oligomeric silsesquioxane, nanocomposite hydrogel with 3-D network was synthesized via radical polymerization. Octavinyl polyhedral oligomeric silsesquioxane was used as crosslinker and nanofiller simultaneously in the preparation of the hydrogel. Hydrogel adsorption performance was determined by adsorption of methylene blue. The adsorption capacity was ev...

novel collagen-based hydrogel nanocomposites were synthesized by graft copolymerization of acrylamide and maleic anhydrid in the presence of different amounts of montmorillonite, using methylenebisacrylamide (mba)and ammonium persulfate (aps) as crosslinker and initiator, respectively. the optimum amount of clay on the swelling properties of the samples was studied. it was found that the hydrog...

Photopolymerized hydrogels are extensively investigated for various tissue engineering applications, primarily due to their ability to form hydrogels in a minimally invasive manner. Although photocrosslinkable hydrogels provide necessary biological and chemical characteristics to mimic cellular microenvironments, they often lack sufficient mechanical properties. Recently, nanocomposite approach...

The limitations associated with the conventional therapeutics have intended the use of controlled drug delivery systems. In recent years, the hydrogel technology has been an integral part of human health care. The pharmaceutical industry has been developing hydrogel based drug delivery system in an advanced manner by tuning the structure, shape and surface modifications of the biopolymers. The ...

In this work, hydrogel nanocomposites were synthesized by solution polymerization of acrylic acid (AA) and itaconic acid (IA) in the presence of cotton fabric. Ammonium persulfate (APS) was used as the polymerization initiator in the presence of a crosslinker, methylene bisacrylamide (MBA). Insertion of Ag followed by reduction of Ag+ cations results in a hydrogel nanocomposite. The ...

Rod-shaped cellulose nanocrystals (CNCs) were manufactured and used to reinforce polyacrylamide (PAM) hydrogels through in situ free-radical polymerization. The gelation process of the nanocomposite hydrogels was monitored on a rheometer using oscillatory shear. The chemical structure, morphology, swelling property, and compression strength of the formed gels were investigated. A possible mecha...