First-principles computational studies indicate that (B, N, or O)-doped graphene ribbon edges can substantially reduce the energy barrier for H2 dissociative adsorption. The low barrier is competitive with many widely used metal or metal oxide catalysts. This suggests that suitably functionalized graphene architectures are promising metal-free alternatives for low-cost catalytic processes.

abstract: this paper is the first study on the impact of ambient temperature on the electrical characteristics and high frequency performances of double gate armchair graphene nanoribbon field effect transistor (gnrfet). the results illustrate that the gnrfet under high temperature (ht-gnrfet) has the highest cut-off frequency, lowest sub-threshold swing, lowest intrinsic delay and power delay ...

We use ab initio density-functional calculations to determine the interaction of a graphene monolayer with the Si(111) surface. We find that graphene forms strong bonds to the bare substrate and accommodates the 12% lattice mismatch by forming a wavy structure consisting of free-standing conductive ridges that are connected by ribbon-shaped regions of graphene, which bond covalently to the subs...

Surface plasmon modes at terahertz-infrared waveband in subwavelength graphene wedge and groove waveguides are investigated, which can be categorized into perfect electric conductor and perfect magnetic conductor symmetric modes with different propagation characteristics. The electromagnetic near-fields are localized strongly in different regions for these two kinds of modes. Moreover, these mo...

J. Appl. Phys. 110, 086101 (2011) Direct imaging of intrinsic molecular orbitals using two-dimensional, epitaxially-grown, nanostructured graphene for study of single molecule and interactions Appl. Phys. Lett. 99, 153101 (2011) Graphene nano-ribbon formation through hydrogen-induced unzipping of carbon nanotubes Appl. Phys. Lett. 99, 143119 (2011) Morphology and structure of monoand few-layer ...

Precise spatial control of materials is the key capability of engineering their optical, electronic, and mechanical properties. However, growth of graphene on Cu was revealed to be seed-induced two-dimensional (2D) growth, limiting the synthesis of complex graphene spatial structures. In this research, we report the growth of onion ring like three-dimensional (3D) graphene structures, which are...

We investigated the thermal conductivity K of graphene ribbons and graphite slabs as the function of their lateral dimensions. Our theoretical model considered the anharmonic three-phonon processes to the second-order and included the angle-dependent phonon scattering from the ribbon edges. It was found that the long mean free path of the long-wavelength acoustic phonons in graphene can lead to...

Topological insulators are bulk insulators that possess robust chiral conducting states along their interfaces with normal insulators. A tremendous research effort has recently been devoted to topological insulator-based heterostructures, in which conventional proximity effects give rise to a series of exotic physical phenomena. Here we establish the potential existence of topological proximity...

Graphene fibres are continuously prepared from universal graphene oxide precursors by a novel hydrogel-assisted spinning method. With assistance of a rolling process, meters of ribbon-like GFs, or GRs with improved conductivity, tensile strength, and a long-range ordered compact layer structure are successfully obtained. Furthermore, we refined our spinning process to obtained elastic GRs with ...

We studied the Klein paradox in zigzag (ZNR) and anti-zigzag (AZNR) graphene nanoribbons. Due to the fact that ZNR (the number of lattice sites across the nanoribbon = N is even) and AZNR (N is odd) configurations are indistinguishable when treated by the Dirac equation, we supplemented the model with a pseudo-parity operator whose eigenvalues correctly depend on the sublattice wavefunctions fo...