In this work, we synthesized a trypsin-stabilized fluorescent gold nanocluster. It was found that sulfide interacted with the nanocluster, which could result in significant fluorescence quenching. With this quenching effect, a fluorescence sulfide sensor was developed. This sensor responded linearly to sulfide in the range of 50 nM to 8 μM, and was capable of detecting sulfide as low as 5.5 nM....

Ulug-Sair Au-Bi-Te-Se mineralization is one prospect for native Au in the Western Tuva, and its origin remains debated. Mineralization consists of gold–sulfide–quartz veins host sedimentary rocks (conglomerates, siltstones, shales), quartz–tourmaline, quartz–carbonate–sericite–altered rocks. To determine origin, we examined mineralogical–geochemical features, formation conditions, fluid sources...

Biomining is the use of microorganisms to extract metals from sulfide and/or iron-containing ores and mineral concentrates. The iron and sulfide is microbially oxidized to produce ferric iron and sulfuric acid, and these chemicals convert the insoluble sulfides of metals such as copper, nickel and zinc to soluble metal sulfates that can be readily recovered from solution. Although gold is inert...

A homogeneous layer of silver sulfide or selenide was coated onto gold nanorods in aqueous solution by exposing Au/Ag core/shell nanorods to S or Se in an oxidizing environment. The formation of the silver chalcogenide layers was confirmed by transmission electron microscopy (TEM) and selective area electron diffraction (SAED). The longitudinal plasmon resonance of the gold nanorods shifted to ...

    Introduction Epithermal deposits are usually found in association with near-surface magmatic-hydrothermal environments with volcanic rocks. According to studies, their formation depth is less than 1.5 km and the temperature for their formation is less than 300 ° C. Epithermal deposits are usually rich in gold to gold-silver and rich in silver and include low sulfide, medium sulfide and hig...

In this paper, gold leaching of a refractory sulfide concentrate by chloride–hypochlorite solution was investigated and effects of stirring speed, temperature and particle size on the leaching rate were reported. Experimental data for leaching rate of gold were analyzed with the shrinking–core model. Results were consistent with chemical reaction control mechanism in the first 1 h of leachin...

The extractive metallurgy of gold is largely driven by mineralogical factors such as gold particle size; association with other minerals; coatings; presence of cyanicides, oxygen consumers, and preg-robbers; presence of refractory gold minerals; locking of submicroscopic gold in sulfide and sulfarsenide mineral structures. Gold process mineralogy address all issues related to gold ore processin...

A highly conducting electronic contact between a strained disilane and Au is demonstrated through scanning tunneling microscope-based single-molecule measurements. Conformationally locked cis diastereomers of bis(sulfide)-anchor-equipped 1,2-disilaacenaphthenes readily form high-conducting junctions in which the two sulfide anchors bind in a bipodal fashion to one gold electrode, providing enou...