Al substitution in goethite is common in soils, and has strong influence on the structure and physicochemical properties of goethite. In this research, a series of Al-doped goethites were synthesized, and characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR) and extended X-...

Natural organic matter (NOM) in surficial or ground water exists as a variety of molecular sizes and complex mixture of polyfunctional organic compounds. Adsorption of these organic compounds onto inorganic colloids can alter the physicochemical properties of the solid. Although many classical adsorption models have been developed, little consideration has been given to desorption modeling, so ...

The adsorption of selenite on goethite (a-FeOOH) has been analyzed with the charge distribution (CD) and the multi-site surface complexation (MUSIC) model being combined with an extended Stern (ES) layer model option. The geometry of a set of different types of hydrated iron-selenite complexes has been calculated using Molecular Orbital / Density Functional Theory (MO/DFT). The optimized geomet...

Reactions of aqueous Fe(II) with Fe and Mn oxides influence heavy metal mobility, transformation of trace organics, and important elemental cycles as Fe precipitates form or dissolve, and as electrons move between aqueous and solid phases. Our objective was to characterize reactions of Fe(II) with important metal oxides, using a suite of complementary tools to investigate the extent and underly...

[1] Goethite (a-FeOOH) is an antiferromagnetic iron oxyhydroxide that forms as a weathering product of iron-bearing minerals. We systematically investigated the lowand room temperature properties of well-defined aluminous goethites [a-(Fe, Al)OOH] with varying grain size and Al content. A marked decrease in the Néel temperature with increasing Al content for goethite lowers the blocking tempera...

The subsurface migration of Pu may be enhanced by the presence of colloidal forms of Pu. Therefore, complete evaluation of the risk posed by subsurface Pu contamination needs to include a detailed physical/chemical understanding of Pu colloid formation and interactions of Pu colloids with environmentally relevant solid phases. Transmission electron microscopy (TEM) was used to characterize Pu n...

Ahstract--Mn-substituted iron oxides were synthesized by coprecipitating Fe(NO3)3 and Mn(SO4) solutions with NH4OH, adjusting the suspensions to pH 4 or 6, and then keeping the suspensions at 55~ for 62 days. The Mn mole fraction of the final products ranged from 0 to 0.3. X-ray powder diffraction patterns showed that goethite and hematite formed in each Fe-containing system. Groutite formed in...

Hexavalent chromium reduction by sulfide in the presence of goethite was studied through several batch experiments. Under our specific experimental conditions including 20 μM of hexavalent chromium, 560–1117 μM of sulfide and 10.61– 37.13 m2/L of goethite at pH of 8.45 controlled by 0.1 M borate buffer, the obtained hexavalent chromium disappearance rate was –d[Cr(VI)]/dt = k[surface area of go...

The mobility of toxic metals and the transformation of organic pollutants in the environment are influenced and in many cases even controlled by iron minerals. Therefore knowing the factors influencing iron mineral formation and transformation by Fe(II)-oxidizing and Fe(III)-reducing bacteria is crucial for understanding the fate of contaminants and for the development of remediation technologi...

An investigation was carried out aiming at assessing the potential of vis-NIR reflectance spectroscopy, through comparison with the conventional X-ray powder diffraction (XRPD) technique, for the characterization of synthetic gleys, obtained in laboratory starting from Fe0 and Fe2+ under different conditions of initial pH (5.5, 7.0 and 8.5). XRPD analysis showed that in any case goethite formed...