نتایج جستجو برای: gdiii

تعداد نتایج: 48  

2018
Florian Mayer Sriram Tiruvadi Krishnan Daniel T. Schühle Svetlana V. Eliseeva Stéphane Petoud Éva Tóth Kristina Djanashvili

Self-aggregating calix[4]arenes carrying four DOTA ligands on the upper rim for stable complexation of paramagnetic GdIII-ions have already been proposed as MRI probes. In this work, we investigate the luminescence properties of TbIII-DOTA-calix[4]arene-4OPr containing four propyl-groups and compare them with those of the analog substituted with a phthalimide chromophore (TbIII-DOTA-calix[4]are...

Journal: :Dalton transactions 2013
Graeme J Stasiuk Sudarsan Tamang Daniel Imbert Christelle Gateau Peter Reiss Pascal Fries Marinella Mazzanti

Three bimodal MRI/optical nanosized contrast agents with high per-nanoparticle relaxivity (up to 2523 mM(-1) s(-1) at 35 MHz and 932 mM(-1) s(-1) at 200 MHz) have been prepared connecting up to 115 tris-aqua Gd(III) complexes to fluorescent non-toxic InP/ZnS quantum dots. The structure of the linker has an important effect on the relaxivity of the final multimeric contrast agent.

Journal: :Journal of the American Chemical Society 2001
D M Doble M Botta J Wang S Aime A Barge K N Raymond

The use of GdIII complexes as contrast agents in magnetic resonance imaging (MRI) has proven invaluable in the diagnosis of several internal abnormalities.1 The range of medical applications for which contrast agents are useful is likely to increase in the future with the development of target-specific contrast agents of increased relaxivity, such as MS-325 which binds with HSA in the blood poo...

Journal: :Dalton transactions 2016
Sui-Jun Liu Chen Cao Shu-Li Yao Teng-Fei Zheng Zheng-Xiang Wang Chao Liu Jin-Sheng Liao Jing-Lin Chen Yun-Wu Li He-Rui Wen

By using Gd2O3, propanedioic acid (H2pda) and oxalic acid (H2ox), a new Gd-based metal-organic framework (MOF) [Gd(pda)(ox)0.5(H2O)2]n (1) has been successfully constructed and structurally characterized. Interestingly, temperature- and vapor-induced reversible single-crystal-to-single-crystal transformations occurred and two new MOFs, namely [Gd(pda)(ox)0.5(H2O)]n (1a) and [Gd(pda)(ox)0.5]n (1...

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