Gadolinium oxide (Gd2O3), which can be used as a T1-weighted magnetic resonance imaging (MRI) contrast agent, has attracted intense attention in recent years. In this paper, ligand-free monoclinic Gd2O3 nanocrystals of 7.1 nm in diameter are synthesized by a simple and green approach, namely microsecond laser ablation of a gadolinium (Gd) target in deionized water. These nanocrystals obtain hig...

Nanoparticles exhibiting both magnetic and luminescent properties are need of the hour for many biological applications. A single compound exhibiting this combination of properties is uncommon. Herein, we report a strategy to synthesize a bifunctional luminomagnetic Gd2-xEuxO3 (x = 0.05 to 0.5) nanorod, with a diameter of ~20 nm and length in ~0.6 μm, using hydrothermal method. Gd2O3:Eu(3+) nan...

The development of upconversion nanoparticles (UCNs) for theranostics application is a new strategy toward the accurate diagnosis and efficient treatment of cancer. Here, magnetic and fluorescent lanthanide-doped gadolinium oxide (Gd2O3) UCNs with bright upconversion luminescence (UCL) and high longitudinal relaxivity (r1) are used for simultaneous magnetic resonance imaging (MRI)/UCL dual-moda...

gd2o3 nanoparticles were prepared by a two–step process; cathodic electrodeposition followed by heat-treatment method. first, gd(oh)3 nanoparticles was galvanostatically deposited from nitrate bath on the steel substrate by pulse current (pc) mode. the deposition experiments was conducted at a typical on-time and off-time (ton=1ms and toff=1ms) for 60 min. the electrodeposited precursor was the...

The synthesis, morphological characterization, and optical properties of colloidal, Eu(III) doped Gd2O3 nanoparticles with different sizes and shapes are presented. Utilizing wet chemical techniques and various synthesis routes, we were able to obtain spherical, nanodisk, nanotripod, and nanotriangle-like morphology of Gd2O3:Eu3+ nanoparticles. Various concentrations of Eu3+ ions in the crystal...

Luminescent hybrid nanoparticles with a paramagnetic Gd2O3 core were applied as contrast agents for both in vivo fluorescence and magnetic resonance imaging. These hybrid particles were obtained by encapsulating Gd2O3 cores within a polysiloxane shell which carries organic fluorophores and carboxylated PEG covalently tethered to the inorganic network. Longitudinal proton relaxivities of these p...

The current work aims to synthesize highly fluorescent and surface-functionalized gadolinium oxide nanoparticles (Gd2O3 NPs) with (3-mercaptopropyl) trimethoxysilane (MPTMS). surface modification of Gd2O3 MPTMS enhanced the stability solubility nanoprobe in aqueous media. size was controlled 7 ± 1 nm using coating. These valued points made MPTMS@Gd2O3 as economical, sensitive, selective a quick...

the geometric-arithmetic index is another topological index was defined as2 deg ( )deg ( )( )deg ( ) deg ( )g guv eg gu vga gu v  , in which degree of vertex u denoted by degg (u). wenow define a new version of ga index as 4( )2 ε ( )ε ( )( )ε ( ) ε ( )g ge uv e g g gu vga g  u v , where εg(u) isthe eccentricity of vertex u. in this paper we compute this new topological index for twogr...

Single-crystal Gd2O3 films were grown epitaxially on GaAs~100! substrate. From the single-crystal momentum space analysis on four different samples, 185, 45, 25, and 18 Å thick, a Mn2O3 isomorphous cubic structure is identified. The Gd2O3 film aligns its twofold ~110! axis with the fourfold ~100! surface normal of the substrate, while aligning its @001# and @ 1̄10# axes with the @011# and @011̄# ...