The chromatographic and ionization properties of 35 polybrominated diphenyl ether (PBDE) congeners were investigated using GC/HRMS with metastable atom bombardment (MAB) and electron impact (EI) ionization. A multiple linear regression model based on bromine substitution patterns and MOPAC calculated physical properties was developed to predict relative GC retention times of individual PBDE con...

Residual solvents are organic volatile impurities that can occur in the manufacture of Active Pharmaceutical Ingredients (APIs). analysis pharmaceutical products is necessary not only because they represent a potential risk for human health due to their toxicity and undesirables side effects, but also may affect physicochemical proprieties product. The main objective this work was 29 residual s...

in the present study, tenorite (cuo) nanoparticles have been assayed for their catalytic properties. the decontamination reaction of chloro ethyl ethyl sulfide (cees) as an surrogate of sulfur mustard simulant have been accomplished on the surface of cuo nps with different weight ratios at ambient temperature and monitored by gas chromatography equipped with flame ionization detector (gc-fid) a...

We introduce a new in-situ instrument, Thermal desorption Aerosol GC/MS-FID (TAG), capable of hourly measurements of speciated organic compounds in atmospheric aerosols. Aerosol samples are collected into a thermal desorption cell by means of humidification and inertial impaction. The sample is thermally desorbed and transferred with helium carrier gas into a gas chromatography (GC) column, wit...

Background: Urinary organic acids are water-soluble intermediates and end products of the metabolism of amino acids, carbohydrates, lipids, and a number of other metabolic processes. In the hereditary diseases known as organic acidurias, an enzyme or co-factor defect in a metabolic pathway leads to the accumulation and increased excretion of one or more of these acidic metabolites. Gas chromato...

A photoionization detector (PID) is well known for its high sensitivity, large dynamic range, and non-destructive vapor detection capability. However, due to its tardy response, which results from the relatively large ionization chamber and dead volume, the application of the PID in gas chromatography (GC) has been limited. Here, we developed a rapid, flow-through, and highly sensitive microflu...

background food born pathogenic bacteria are the most important agents of infections in humans, and food spoilage also results in economic losses in food industry. objectives the aim of this study was the evaluation of chemical components, total phenolic content, antioxidant and antibacterial activities of artemisia dracunculus essential oil. materials and methods the essential oil of tarragon ...

background: nanotechnology is a new approach that has been lionized in recent years. one of its applications is its consumption as an absorbent. in this study, the single-wall carbon nanotubes (swcnts) were used as an absorbent for sampling benzene in the air. materials and methods: for this study, swcnts manufactured by iran and skc’s activated charcoal were used for sampling benzene vapors. p...

two modified methods for assaying sodium diclofenac were developed by gc and hplc. diclofenac was converted into methyl ester derivative by methyl iodide in acetone. the ester was extract and subjected to glc with flame ionization detector. %5 se-30/chrom w-hp (80-100 mesh) was used as a column in gc. for reversed phase hplc, the mobile phase was methanol and water (55-45). the separation was p...