Electrochemical nucleation at a liquid j liquid interface has been studied by cyclic voltammetry and galvanostatic measurements. A model of general applicability to any current/potential transient was developed for three-dimensional nucleation and growth, yielding information on particle number density. The experimental data was analyzed with this model. # 2002 Elsevier Science B.V. All rights ...

A novel galvanostatic intermittent titration technique (GITT) and a novel potentiostatic intermittent titration technique (PITT) for phase-transformation electrodes were developed by integrating mixed control phasetransformation theory with traditional GITT and PITT methods. The contribution of the strain accommodation energy to the thermodynamic driving force for phase transformation was asses...