Three-dimensional (3D) nanomagnetism, where spin configurations extend into the vertical direction of a substrate plane allow for more complex, hierarchical systems and the design of novel magnetic effects. As an important step towards this goal, we have recently demonstrated the direct-write fabrication of freestanding ferromagnetic 3D nano-architectures of ferromagnetic CoFe in shapes of nano...

The fabrication of freestanding, sub-100 nm-thick, pH-responsive hydrogel membranes with controlled nano-morphology, based on modified poly(hydroxyethyl methacrylate) (PHEMA) is presented. Polymer hydrogel-brush films were first synthesized by surface-initiated atom transfer radical polymerization (SI-ATRP) and subsequently detached from silicon substrates by UV-induced photo-cleavage of a spec...

Graphene oxide (GO) based membranes have been widely applied in molecular separation based on the size exclusion effect of the nanochannels formed by stacked GO sheets. However, it's still a challenge to prepare a freestanding GO-based membrane with high mechanical strength and structural stability which is prerequisite for separation application in aqueous solution. Here, a freestanding compos...

Compared to freestanding nanoparticles, supported nanostructures typically show better mechanical stability as well as ease of handling. Unique shapes such as core-shells, raspberries and crescents have been developed on supported materials to gain improved chemical and optical properties along with versatility and tunability. We report the formation of hyper-branched gold structures on silica ...

A new device is presented for the combinatorial analysis of complex nano-scale material systems. The parallel nano-differential scanning calorimeter (PnDSC) is a micro-machined array of calorimetric cells. This new approach to combinatorial calorimetry greatly expedites the analysis of nano-scale material thermal properties. A power-compensation differential scanning calorimetry measurement is ...

This paper presents a novel experimental–theoretical method to investigate the strength of structures having complex geometries, which are commonly used in microelectromechanical systems (MEMS). It involves the stretching to failure of freestanding thin-film membranes, in a fixed–fixed configuration, containing micro-fabricated sharp cracks, blunt notches and re-entrant corners. The defects, ma...

Structural degradation and low conductivity of transition-metal oxides lead to severe capacity fading in lithium-ion batteries. Recent efforts to solve this issue have mainly focused on using nanocomposites or hybrids by integrating nanosized metal oxides with conducting additives. Here we design specific hierarchical structures and demonstrate their use in flexible, large-area anode assemblies...

We report an alternative technique which utilizes fast proton or helium ion irradiation prior to electrochemical etching for three-dimensional micro-fabrication in bulk p-type silicon. The ion-induced damage increases the resistivity of the irradiated regions and slows down porous silicon formation. A raised structure of the scanned area is left behind after removal of the un-irradiated regions...

STUDY OBJECTIVE We compare utilization, price per visit, and the types of care delivered across freestanding emergency departments (EDs), hospital-based EDs, and urgent care centers in Texas. METHODS We analyzed insurance claims processed by Blue Cross Blue Shield of Texas from 2012 to 2015 for patient visits to freestanding EDs, hospital-based EDs, or urgent care centers in 16 Texas metropol...

Freestanding and bound morphemes differ in many (psycho)linguistic aspects. Some theorists have claimed that the representation and retrieval of freestanding and bound morphemes in the course of language production are governed by similar processing mechanisms. Alternatively, it has been proposed that both types of morphemes may be selected for production in different ways. In this article, the...