in the present research work, the kinetics of sunflower oil transesterification reaction in the presence of ba-sr/zsm-5 nanocatalyst which prepared using incipient wetness impregnation method was investigated. the 10wt.%ba-sr/zsm-5 (sr/ba=3/2) nanocatalyst was calcined at 600 °c for 6 h with a heating rate of 3 ºc/min. the experimental conditions were the methanol/oil 9/1molar ratio, reaction t...

reactions of free radicals and reactive oxygen species (ros) with biological molecules in vivo play an important physiological role in many diseases. 2,2-diphenyl-1-picrylhydrazyl (dpph) is a stable free radical and often used as a routine reagent to evaluate the antioxidant capacity of an antioxidant. this study was undertaken to investigate the free radical-scavenging and antioxidant activiti...

the armaticity of 5 methylcytosine tautomers in the gas phase has been studied and the chemical structures of related tautomers are investigated . the electronic energy, enthalpy and free energy of each tautomer are also estimated at the b3lyp/6-31 g* // b3lyp/6-31 g* and mp2 / 6-31 g* // mp2 / 6-31 g* levels

Oils of vegetable origin are of great importance in food, soap, and cosmetic industries and they may also be used as lubricants and raw materials for biodiesel production depending on their viscosity and thermal stability. This work provides insight into the fatty acid components, physicochemical properties and thermal stability of some refined vegetable oils. The Saponification values, peroxid...

gasification is a well-known reaction owing to its relevance to generation of sustainable energyfrom biomass and development of porous carbons. the present paper attempts to experimentally investigate the kinetics of palm shell char gasification using carbon dioxide (co2) in a controlled environment using thermo gravimetric analyzer (tga) at temperatures ranging from 800 to1000°c. a relevant ki...

Schiff base complexes of transition metals are of particular interest to inorganic chemists because of their structural, spectral and chemical properties, which are often strongly dependant on the nature of the ligand structure. Large number of metal (II) complexes with Schiff-base ligands has been extensively studied for their interesting structural specialties, applications and properties. Th...

In the present paper, electrical energy harvesting from random vibrations of an Euler-Bernoulli nano-beam with two piezoelectric layers is investigated. The beam is composed of an aluminum layer together with two piezoelectric ceramic layers (PZT 5A) serving as energy harvesting sensors. In the proposed method, the equations governing the bimorph nano-beam will be analytically derived using cla...