fe3o4 nanoparticles were synthesizedviaa simple chemical reaction between fecl2.4h2o and fe(no3)3.9h2o under nitrogen atmosphere at room temperature, and then nanoparticles were added to cellulose acetate (ca) polymer. the influence of nanoparticles on the thermal properties of ca polymeric matrix was studied using thermogravimetric analysis (tga). nanostructures were characterized by x-ray dif...

This paper aims to develop a novel method, i.e., sol-gel combined with layer-by-layer assembly technology, to impart flame retardancy on polyacrylonitrile (PAN) fabrics. Silica-sol was synthesized via the sol-gel process and acted as cationic solution, and phytic acid (PA) was used as the anionic medium. Flame-retardant-treated PAN fabric (FR-PAN) could achieve excellent flame retardancy with 1...

BACKGROUND Children are exposed to flame retardants from the built environment. Brominated diphenyl ethers (BDE) and organophosphate-based flame retardants (OPFRs) are associated with poorer neurocognitive functioning in children. Less is known, however, about the association between these classes of compounds and children's emotional and social behaviors. The objective of this study was to det...

An HPLC-UV/MS method has been developed to identify and quantify flame retardants in post-consumer plastics from waste of electric and electronic equipment (WEEE). Atmospheric pressure chemical ionisation spectra of 15 brominated and phosphate-based flame retardants were recorded and interpreted. The method was applied to detect flame retardant additives in polymer extracts obtained from pressu...

A new synergetic flame retardant system (SFRS) using ammonium polyphosphate/melamine cyanurate (APP/MCA) core-shell particle was synthesized and applied to papermaking. Cationic polyacrylamide (CPAM) was added to improve the adsorption of SFRS in pulp. Higher amounts of SFRS led to higher adsorption by pulp. Handsheets were produced with different amounts of SFRS. Thermal gravimetric analysis (...

BACKGROUND Flame retardant chemicals are used in materials on airplanes to slow the propagation of fire. These chemicals migrate from their source products and can be found in the dust of airplanes, creating the potential for exposure. METHODS To characterize exposure to flame retardant chemicals in airplane dust, we collected dust samples from locations inside 19 commercial airplanes parked ...

Preface In 2005 Norway nominated the brominated flame retardant commercial pentabromodiphenylether (c-PentaBDE) as a persistant organic pollutant (POP) to be evaluated for inclusion in the Stockholm Convention. Based on its Risk Profile developed in 2006 and its Risk Management Evaluation Report developed in 2007, the POPs Review Committee (POPRC) concluded that global action on c-PentaBDE is w...

A novel flame retardant, zinc hydroxystannate-decorated graphene oxide (ZHS/GO) nanohybrid, was successfully prepared and well characterized. Herein, the ZHS nanoparticles could not only enhance the flame retardancy of GO with the synergistic flame-retardant effect of ZHS but also prevent the restack of GO to improve the mechanical properties of poly (vinyl chloride) (PVC) matrix. The structure...

Enhanced Heat Release Rate (HRR) methodology has been extended to the Mass Loss Calorimeter (MLC) and the Modified Schlyter flame spread test to evaluate fire retardant effectiveness used on wood based materials. Modifications to MLC include installation of thermopile on the chimney walls to correct systematic errors to the sensible HRR calculations to account for radiant energy losses to the c...

This paper presents an analysis of the use of red phosphorus as a flame retardant material in encapsulated microcircuits and discusses the reliability risks. Chemical reactions, which can arise when red phosphorus is exposed to ambient humidity to form highly mobile ions and oxygen-containing phosphorus acids, are presented. These ions and acids can induce electro-chemical migration, causing sh...