The effect of L-ascorbic acid 2-[3,4-dihydro-2,5,7,8-tetramethyl-2-(4,8,12-trimethyltridecyl)-2H -1-benzopyran-6-yl-hydrogen phosphate] potassium salt (EPC-K1) on hydroxyl radical (*OH) elimination was studied using electron spin resonance (ESR) and spectrophotometric experiments. The addition of EPC-K, and *OH scavengers eliminated the *OH generated from Cu2+/H2O2, Fe2+/H2O2 and H2O2/UV-irradi...

Background & Aims of the Study: Phenolic compounds have been extensively used in industries for applications such as petrochemical, oil refineries, papers, plastics, steel, pharmaceuticals, textiles, coal conversion, and so on. Specified amounts of Phenolic compounds are lost in the process of their manufacturing and utilization and often cause environmental pollution problems....

The application of synthetic colors in textile industries and their entry into the water and groundwater is an environmental problem because of being very toxic material. The synthetic colors which are used in textile dyeing (plyacrilic and polyester) are usually dispersing colorants. They derive the azo and anthraquinone chemicals. Electro-Fenton process is an efficient technique which can deg...

Advanced Oxidation Processes (AOPs) have been employed to degrade biorefractory organic matters. This study investigates the combination of classical Fenton reaction with electrochemical oxidation, the electro-Fenton process, for the treatment of semi aerobic landfill leachate, collected from Pulau Burung Landfill Site (PBLS), Penang, Malaysia. The investigation has been carried out in batch re...

Advanced Oxidation Processes (AOPs) have been employed to degrade biorefractory organic matters. This study investigates the combination of classical Fenton reaction with electrochemical oxidation, the electro-Fenton process, for the treatment of semi aerobic landfill leachate, collected from Pulau Burung Landfill Site (PBLS), Penang, Malaysia. The investigation has been carried out in batch re...

In this study, the Fenton process was applied for the degradation of carbofuran from aqueous system. Batch experiments were conducted at two different carbofuran concentrations i.e., 10 and 50 mg/L, and at pH 3. Batch experiments at each carbofuran concentration were designed by central composite design (CCD) with two independent variables i.e. Fe2+ and H2O2. Experimental results indicate that ...

Both O2 and H2O2 can oxidize iron at the ferroxidase center (FC) of Escherichia coli bacterioferritin (EcBfr) but mechanistic details two reactions need clarification. UV/Vis, EPR, Mössbauer spectroscopies have been used to follow when apo-EcBfr, pre-loaded anaerobically with Fe2+, was exposed or H2O2. We show that binds di-Fe2+ FC reversibly, Fe2+ ions are oxidized in concert a molecule is for...

Superoxide (O2-.) was reduced by the addition of superoxide dismutase (SOD: O2-. scavenger) and catechins. In competitive reactions utilizing different concentrations of spin-trap agent, the IC50 values of each sample were changed. With regard to the Cu2+/H2O2 and Fe2+/H2O2 reaction systems, metal chelater, hydroxyl radical (.OH) scavenger and catechins eliminated the levels of .OH. For the Cu2...

The aim of this research was to evaluate the effective parameters such as pH, current density (mA/cm2), H2O2/Fe2+ molar ratio, volume ratio of H2O2 to pharmaceutical wastewater (PhW) (ml/l) and reaction time (min) on the electro-Fenton process for the ibuprofen (as a pharmaceutical waste in water) removal. Since a synthetic wastewater with the same concentration of ibuprofen in a real pharmaceu...