The influence of Fe(III) starting material on the ability of magnetically recoverable biogenic magnetites produced by Geobacter sulfurreducens to retain metal oxyanion contaminants has been investigated. The reduction/removal of aqueous Cr(VI) was used to probe the reactivity of the biomagnetites. Nanomagnetites produced by the bacterial reduction of schwertmannite powder were more efficient at...

In this study, a novel and environmentally benign o-phenylendiamine stabilized on silica-coated Fe3O4 magnetic nanocatalyst (Fe3O4@SiO2@propyltriethoxysilane@o-phenylendiamine-SO3H/HCl) as a hybrid magnetic organometallic nanocatalyst has been synthesized. After that, the structure of this new catalyst was compl...

Hexavalent chromium (Cr(vi), present predominantly as CrO4(2-) in water at neutral pH) is a common ground water pollutant, and reductive immobilization is a frequent remediation alternative. The Cr(iii) that forms upon microbial or abiotic reduction often co-precipitates with naturally present or added iron (Fe), and the stability of the resulting Fe-Cr precipitate is a function of its mineral ...

A novel magnetically recoverable and recyclable nanocatalyst, Cu 2 O-Fe 3 O 4 @TNT, has been developed for the synthesis of 1,4-disubstituted 1,2,3-triazoles at room temperature in aqueous medium.

The present investigation deals with the accumulation of heavy metals in fields contaminated with fly ash from a thermal power plant and subsequent uptake in different parts of naturally grown plants. Results revealed that in the contaminated site, the mean level of all the metals (Cd, Zn, Cr, Pb, Cu, Ni, Mn and Fe) in soil and different parts (root and shoots) of plant species were found to be...

Cu(0) nanoparticles were deposited on a nanoporous polymer to develop a novel nanocatalyst (Cu-B) for carrying out Ullmann coupling of aryl halides with amines in water. Non-aqueous polymerization of a mixture of divinylbenzene and acrylic acid under hydrothermal conditions followed by the deposition of Cu(0) nanoparticles were adopted to afford the Cu-B nanocatalyst. In order to compare the ca...

Various morphologies of multi-walled carbon nanotubes (MWNTs) are grown catalytically on metalalloy probes in counterflow diffusion flames using methane as fuel. Carbon nanotube (CNT) properties and morphologies are investigated as functions of local gas-phase temperatures, C-related species concentrations (e.g. C2H2, CO), sampling positions, C2H2 adding to the fuel, and metal-alloy composition...

Fe-Cr alloy layers on Fe 001 substrates with different atomic environments are theoretically investigated through a self-consistent real-space tight-binding method parametrized to density functional theory and without collinear restriction for the spin directions. We show that the intermixing at the Cr/Fe interface, experimentally observed at the first stages of the Cr growth on Fe, originates ...

The slurry erosion behaviour of laser clad Fe–Cr–B–Si alloy coatings was investigated at impact angles from 30u to 90u with an increment of 15u, and compared with the slurry erosion behaviour of two laser clad carbide coatings and a non-coated substrate made of AISI 4140 steel. The Fe–Cr–B–Si alloy coatings had slurry erosion resistance. Their overall slurry erosion resistance at impact angles ...