The emission spectra of luminescent trivalent europium (Eu3+) and terbium (Tb3+) complexes were measured using a microscope laser Raman spectrometer with a doubled Nd:YAG laser (532 nm) and an Ar laser (488 nm). Excitation at 532 and 488 nm corresponded to wavelengths of the 7F1 --> 5D1 band of Eu3+ and the 7F6 --> 5D4 band of Tb3+, respectively. The Eu3+ and Tb3+ complexes were discriminated b...

Lanthanide-doped nanocrystals (NCs) differ from their bulk counterparts due to their large surface to volume ratio. It is generally assumed that the optical properties are not affected by size effects as electronic transitions occur within the well-shielded 4f shell of the lanthanide dopant ions. However, defects and disorder in the surface layer can affect the luminescence properties. Trivalen...

In this investigation, Eu3+ doped YVO4 /YBO3 phosphors were synthesized individually by conventional solid state method at 1100 °C under atmosphere condition. Meanwhile, different amounts of LiClwere used as the flux compound to modify the morphology of the phosphor particles and also final luminescence properties. It was concluded that even small amounts of fluxes play a vital role in the grow...

Europium-doped bismuth silicate (Bi4Si3O12) phosphor has been prepared by microwave irradiation method and its crystal structure is determined using Rietveld method. As-prepared phosphor consists of spherical, monodispersed particles with few agglomeration, high crystallinity, and narrow grain size distribution. The phosphor can be efficiently excited in the wavelength range of 260-400 nm, whic...

Near infrared (NIR)-emitting persistent luminescent nanoparticles have been developed as potential agents for bioimaging. However, synthesizing uniform nanoparticles with long afterglow for long-term imaging is lacking. Here, we demonstrated the synthesis of spinel structured Zn3Ga2Ge2O10:Cr3+ (ZGGO:Cr3+) and Zn3Ga2Ge2O10:Cr3+,Eu3+ (ZGGO:Cr3+,Eu3+) nanoparticles by a sol-gel method in combinati...

In this work, we study the energy transfer mechanism from ZnO nanocrystals (ZnO-nc) to Eu3+ ions by fabricating thin-film samples of ZnO-nc and Eu3+ ions embedded in a SiO₂ matrix using the low-cost sol-gel technique. The time-resolved photoluminescence (TRPL) measurements from the samples were analyzed to understand the contribution of energy transfer from the various ZnO-nc emission centers t...

Eu3+-modified carbon dots (C-dots), 3-5 nm in diameter, were prepared, functionalized, and stabilized via a one-pot polyol synthesis. The role of Eu2+/Eu3+, the influence of O₂ (oxidation) and H₂O (hydrolysis), as well as the impact of the heating procedure (conventional resistance heating and microwave (MW) heating) were explored. With the reducing conditions of the polyol at the elevated temp...

7-Amino-4-trifluoromethyl-2-(1H)-quinolinone (cs124-CF3), has been synthesized and found to be an effective antenna molecule (or sensitizer) for europium, but not terbium, luminescence. Specifically, cs124-CF3 has been covalently attached to the chelates diethylenetriaminepentaacetic acid (DTPA) and triethylenepentamine-hexanoic acid (TTHA). When bound to europium, excitation in the absorption ...

A novel kind of organic-inorganic monomer SUASi has been achieved by modifying 5-sulfosalicylic acid (SUA) with 3-aminopropyltrimethoxysilane (APS), subsequently binary and ternary Eu3+ mesoporous hybrid materials with 5-sulfosalicylic acid (SUA)-functionalized SBA-15 and 1,10-phenanthroline (phen) are synthesized by co-condensation of SUASi and TEOS in the presence of Eu3+ complex and Pluronic...

Calcium phosphate is the most important inorganic constituent of biological tissues, and synthetic calcium phosphate has been widely used as biomaterials. In this study, a facile method has been developed for the fabrication of amorphous calcium phosphate (ACP)/polylactide-block-monomethoxy(polyethyleneglycol) hybrid nanoparticles and ACP porous nanospheres. Europium-doping is performed to enab...