An Erbium(III) quaternary chelate, nitratebis(2,4-hexanedionate)mono(2,2-bipyridine) erbium(III), has been synthesized and its structure elucidated by X-ray diffraction. There are two independent lanthanide complexes in the asymmetric unit cell. The ligands coordinate the Er(III) in a square anti-prismatic geometry. In the theoretical part of this study, semi-empirical quantum chemistry methods...

The use of sol-gel to fabricate silica-on-silicon waveguides, and particularly erbium-doped waveguide amplifiers, is reviewed. In particular, efforts to use sol-gel to improve molecular homogeneity in heavily Er-doped silica-based films is discussed. A variety of material studies carried out to investigate the gain limitations found in these materials is then presented. These include x-ray diff...

The »truncated crystal field method« which allows determination of the microsymmetry of the crystal field around Kramers . ions is applied to erbium(III) in five different host crystals. The starting data for the calculations are taken from carefully interpreted optical spectra. In the first step, crystal field narameters for various assumed test symmetries are chosen in order to give the best ...

The absorption spectra of the 4f electron transitions of neodymium, praseodymium, holmium and erbium complexes with fleroxacin in the presence of cetylpyridinium chloride were studied by normal and derivative spectrophotometry. Their molar absorptivity at the maximum absorption bands are about 5.3 (at 571 nm) times greater for neodymium, 2.8 (at 483 nm) times greater for praseodymium, 12.6 (at ...

Alkylated silicon nanocrystals (C11-SiNCs) were prepared successfully by galvanostatic etching of p-Si(100) wafers followed by a thermal hydrosilation reaction of 1-undecene in refluxing toluene in order to extract C11-SiNCs from porous silicon. Erbium trichloride was added to alkylated SiNCs using a simple mixing chemical route. To the best of our knowledge, this is the first investigation on ...

The objective of this literature review was to critically review the evidence available in the literature regarding the expediency of erbium family of lasers for root bio modification as a part of periodontal therapy. The literature search was performed on the Pubmed using MeSH words such as "lasers/therapeutic use, scaling, dental calculus, tooth root/anatomy and histology, ultrasonic therapy"...

A fiber made by Furnace CVD was codoped with Erbium and Magnesium using a Flash Vaporization System for the first time. The fiber core is spontaneously formed as a Transparent Glass Ceramic (TGC). Due to the small nanoparticle size (<50 nm) and high volumetric density (10~10 m), the optical loss due to scattering is as low as < 0,6 dB/m. Erbium ions are highly concentrated within phase-separate...

A new route was recently proposed to modify some spectroscopic properties of rare-earth ions in silica-based fibers. We had shown the incorporation of erbium ions in amorphous dielectric nanoparticles, grown in fiber preforms. Here we present the achieved stabilization of nanometric erbium-doped dielectric nanoparticles within the core of silica fibers. We present the nanoparticle dimensional c...