Simultaneous acquisition of in vivo electrophysiological and neurochemical information is essential for understanding how endogenous neurochemicals modulate the dynamics of brain activity. However, up to now such a task has rarely been accomplished due to the major technical challenge of operating two independent recording systems simultaneously in real-time. Here we propose a simpler solution ...

The introduction of oxygen in electrochemical oxidation at relatively high temperature and pressure as a promoter resulting in synergetic effects, greatly improves the mineralization of high-concentrated organic pollutants.

the applications of electrochemical machining are increasing because of increasing requests of industries for materials with high strengh and high hardness. regular ecm uses a tool with spicified profile shape that is similar to final shape of workpiece. in this reasearch a nozzle that delivers electrolyte to the machining gap is used for machining cylinderical workpieces. by moving the electro...

We consider electroconvective fluid flows initiated by ion concentration polarization (ICP) under pressure-driven shear flow, a scenario often found in many electrochemical devices and systems. Combining scaling analysis, experiment, and numerical modeling, we reveal unique behaviors of ICP under shear flow: a unidirectional vortex structure, its height selection, and vortex advection. Determin...

Biological tissues like intervertebral discs and articular cartilage primarily consist of interstitial fluid, collagen fibrils and negatively charged proteoglycans. Due to the fixed charges of the proteoglycans, the total ion concentration inside the tissue is higher than in the surrounding synovial fluid (cation concentration is higher and the anion concentration is lower). This excess of ion ...

The first hyphenation of high performance liquid chromatography (HPLC), electrochemical online oxidation and mass spectrometry (MS) is described. Ferrocenecarboxylic acid esters of various alcohols and phenols have been synthesized, separated by reversed-phase HPLC and oxidized (ionized) coulometrically prior to single quadrupole MS analysis using electrospray ionization (ESI) and atmospheric p...

We discuss our experimental progress toward energyefficient electrochemical CO2 capture from the atmosphere. First we discuss the latest results from an ongoing project that uses a modified-fuel-cell-based approach for CO2 concentration [1]. Using this approach, we have demonstrated CO2 capture from atmospheric concentrations with an energy consumption of less than 400 kJ/mol(CO2). We also disc...

Electrochemical nitrogen-to-ammonia fixation is emerging as a sustainable strategy to tackle the hydrogen- and energy-intensive operations by Haber-Bosch process for ammonia production. However, current electrochemical nitrogen reduction reaction (NRR) progress is impeded by overwhelming competition from the hydrogen evolution reaction (HER) across all traditional NRR catalysts and the requirem...

In this study, a new metal hydride heat pump system driven by an electrochemical compressor was proposed.The system uses the electrochemical compressor to generate absorption heating and desorption cooling in two identical LaNi5 reactors operating at different pressure levels. A thermodynamic model was developed to predict the system performance in terms of various parameters. Modeling shows EC...

This paper presents a framework for the optimal design of experiments for medical sensors calibration. A new software program, G-optimal, is developed to demonstrate the optimal design of experiment. This program has been used to find G-optimal design for amperometric enzyme glucose sensor, silicon capacitive absolute pressure sensors and electrochemical oxygen and carbon dioxide partial pressu...