A general circuit model is derived for the electrical noise of electrode–electrolyte systems, with emphasis on its implications for electrochemical sensors. The noise power spectral densities associated with all noise sources introduced in the model are also analytically calculated. Current and voltage fluctuations in typical electrode–electrolyte systems are demonstrated to originate from eith...

An important signaling process in the nervous system is the release of chemical messengers called neurotransmitters from neurons. In this thesis alternative thin film electrode materials for applications targeting electrochemical detection of neurotransmitters in chip devices were evaluated. Microelectrodes made of the conductive polymer Pedot:tosylate were characterized with respect to their p...

The effect of Mentha spicata L. extract on the corrosion behaviour of carbon steel in 1.0 M HCl solution was investigated using polarization, electrochemical impedance spectroscopy (EIS) and electrochemical noise (EN) techniques. The solution containing 250 ppm of the ethanolic solution of extract showed the highest inhibition efficiency (IE). The effect of temperature on the rate of corrosion ...

The effects of noise on phase synchronization (PS) of coupled chaotic oscillators are explored. In contrast to coupled periodic oscillators, noise is found to enhance phase synchronization significantly below the threshold of PS. This constructive role of noise has been verified experimentally with chaotic electrochemical oscillators of the electrodissolution of Ni in sulfuric acid solution.

Electrochemical noise data is commonly used to monitor corrosion of metals in various environments. In this work we use recurrence plots to study electrochemical noise time series of stainless steel AISI 316 samples immersed in mildly corrosive electrolyte. It has been found that current and potential time series reveal different information. Recurrence quantification analysis of current time s...