In the present work several Pt-based anode catalysts supported on carbon XC-72R were prepared with a novel method and characterized by means of XRD, TEM and XPS analysis. It was found that all these catalysts are consisted of uniform nanosized particles with sharp distribution and Pt lattice parameter decreases with the addition of Ru or Pd and increases with the addition of Sn or W. Cyclic vol...

Analytical models provide useful information for researchers to study fuel cell function. In this paper, it’s aimed to present a 2D analytical model for direct ethanol fuel cell (DEFC) performance. The model included equations inside diffusion layer, catalyst layer, and Ethanol cross-over through membrane, which all have been solved. Analytical model has been validated by some experimental tria...

In this paper, raspberry hollow Pd nanospheres (HPNs)-decorated carbon nanotube (CNT) was developed for electro-oxidation of methanol, ethanol, and formic acid in alkaline media. The electrocatalyst was fabricated simply by attaching HPNs onto the surface of CNT which had been functionalized by polymer wrapping. The as-prepared HPN-CNTs (CHPNs) were characterized by transmission electron micros...

In this study, Nd-doped cobalt oxide (Nd-Co3O4) nanoparticles were prepared by a combustion synthesis procedure using Co(acac)3 complex. The nanoparticles were characterized by infrared spectroscopy (IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). Then, the effect of Nd-Co3O4 ...

This paper reports on a single alkaline exchange membrane direct formate fuel cell (AEM DFFC) consisting of a carbon-supported palladium catalyst at the anode, a quaternized polysulfone membrane, and a non-precious Fe–Co catalyst at the cathode. It is demonstrated that the AEM DFFC yields a peak power density of 130 mW cm 2 with 5 M potassium formate (HCOOK) at 80 C. It is further shown that wi...

Passive direct methanol fuel cell (DMFC) is considered as an attractive power source for portable devices. In this study, a transient multiphase model for passive alkaline anion exchange membrane DMFC (AAEMDMFC) is developed. The results show that the power density decreases during the operation and is more difficult to maintain stable with higher current density or lower voltage. The fuel effi...

Human mesangial cells grown in culture have been employed to investigate the interaction between exposure to ethanol and alkaline phosphodiestase I activity at the plasma membrane of intact cells. Chronic exposure of human mesangial cells to ethanol induced a dose-dependent rise in enzyme activity. Similar effect was observed after the treatment of mesangial cells with methanol. Short-term (1-3...

Local changes of the interfacial pH can significantly affect the rate and mechanism in the course of an electrodic reaction. For instance, different pH values will have significant effect on the equilibrium properties of both solution and surface species altering the reactions kinetics. Ethanol oxidation at platinum electrodes, in alkaline media involves a fast consumption of OH species that wi...