A Cu2+/l-cysteine bilayer-coated microcantilever undergoes bending upon exposure to dimethyl methyl phosphonate at concentration as low as 10-15 M due to the complexation of a phosphonyl group with the Cu2+/l-cysteine bilayer on the microcantilever surface.

Sensitive, selective and fast detection of chemical warfare agents is necessary for anti-terrorism purposes. In our search for functional materials sensitive to dimethyl methylphosphonate (DMMP), a simulant of sarin and other toxic organophosphorus compounds, we found that zinc oxide (ZnO) modification potentially enhances the absorption of DMMP on a manganese dioxide (MnO(2)) surface. The adso...

Chemical warfare agents(CWA) such as nerve agents and vesicating show lethality by skin contamination. Skin protection, therefore, is one of the top priorities to deal with growing threat from CWA. In an attempt develop most effective topical protectant(TSP), candidate substances including PFPE(perfluorinated polyether), PTFE(polytetrafluoroethylene), glycerin, polysaccharides were evaluated in...

Distributed sensing of gas-phase chemicals using highly sensitive and inexpensive sensors is of great interest for many defense and consumer applications. In this paper we present ppb-level detection of dimethyl methylphosphonate (DMMP), a common simulant for sarin gas, with a ppt-level resolution using an improved capacitive micromachined ultrasonic transducer (CMUT) as a resonant chemical sen...

Developing methods to detect, adsorb, and decompose chemical warfare agents (CWAs) is of critical importance to protecting military and civilian populations alike. The sorption of dimethyl methylphosphonate (DMMP), a CWA simulant, into trisilanolphenyl-POSS (TPP) films has previously been characterized with reflection absorption infrared spectroscopy, x-ray photoelectron spectroscopy, and uptak...

LiTMP metalated dimethyl N-Boc-phosphoramidates derived from 1-phenylethylamine and 1,2,3,4-tetrahydronaphthalen-1-ylamine highly selectively at the CH3O group to generate short-lived oxymethyllithiums. These isomerized to diastereomeric hydroxymethylphosphonamidates (phosphate–phosphonate rearrangement). However, s-BuLi converted the dimethyl N-Boc-phosphoramidate derived from 1-phenylethylami...

tio2 nanoparticles, as a photocatalyst for oxidation of dimethyl methylphosphonate (dmmp) as an organophosphorus simulant of chemical warfare agent, were prepared by using sol-gel method. the prepared nanoparticles were then modified with transition metals in order to decrease the electron-hole recombination and increase the photocatalytic activity. transition metal ions including pt, pd and ni...

TiO2 nanoparticles, as a photocatalyst for oxidation of dimethyl methylphosphonate (DMMP) as an organophosphorus simulant of chemical warfare agent, were prepared by using sol-gel method. The prepared nanoparticles were then modified with transition metals in order to decrease the electron-hole recombination and increase the photocatalytic activity. Transition metal ions including Pt...