A route to cationic tungsten alkylidyne N-heterocyclic carbene (NHC) complexes of the general formula [W(CR)X2(NHC)(tBuCN)y+B(ArF)4–] (R = tBu, C6H4-4-OMe; X Br, Cl, OTf; NHC 1,3-dimesityl-1,3-dihydro-2H-imidazol-2-ylidene, IMes; 1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene, IDipp; 1,3-dimesityl-4,5-dichloro-1,3-dihydro-2H-imidazol-2-ylidene, IMesCl2; y 1, 2; ArF 3,5-bis(tri...

treatment of acetyl- 1,4-benzoquinone with isoprene gave the corresponding regioselective adduct (i). rearrangement of the adduct (1) in pyridine and methanol gave 2-acetyl-5, 8-dihydro-6-methyl- 1,4-dihydroxynaphthalene (2). silver oxide oxidation of the rearranged product (2) gave 2-acetyl-5,8-dihydro- 6-methyl- 1,4naphthalenedione (3). regioselective addition of trans-piperylene to this comp...

the genus boswellia is one of the 17 genera belonging to burseraceae family. in this study resin of boswellia carteri birdwoodcollected or purchased from tehram herbal market as a food and non-food for chemical analysis. the essential oils of the resins of boswellia carteri birdwoodobtained by different methods of distillation (water distillation, steam distillation and hydro-steam distillation...

Five new: 21,23-dihydro-21-hydroxy-23-oxonomilin (1), 21,23-dihydro-23-methoxy-21-oxonomilin (2), 21,23-dihydro-21-hydroxy-23-oxonomilinic acid methyl ester (3), 21,23-dihydro-23-methoxy-21-oxolimonin (4), and 21,23-dihydro-21-oxolimonin (5), and seven known limonoids were isolated from peels of satsuma orange (Citrus reticulata). The isolated compounds were evaluated for their inhibitory effec...

A series of phthalimide derivatives planned as drugs candidates to treat the symptoms of sickle cell anemia were evaluated in a mutagenicity test using strains of Salmonella typhimurium TA100 and TA102, without and with addition of S9 mixture, with the aim to identify the best structural requirements for a drug candidate without genotoxic activity. The compounds (1,3-dioxo-1,3-dihydro-2H-isoind...

Treatment of acetyl- 1,4-benzoquinone with isoprene gave the corresponding regioselective adduct (I). Rearrangement of the adduct (1) in pyridine and methanol gave 2-acetyl-5, 8-dihydro-6-methyl- 1,4-dihydroxynaphthalene (2). Silver oxide oxidation of the rearranged product (2) gave 2-acetyl-5,8-dihydro- 6-methyl- 1,4naphthalenedione (3). Regioselective addition of trans-piperylene to this...

the biliary excretion and blood/plasma ratios of four novel 5-bromo-6-alkoxy- 5,6-dihydro prodrugs to s-ethyl-2'-deoxyuridine (edu) including (-)-trans-(5s, 6s)-s-bromo-s-ethyl-6-methoxy-s, 6-dihydro-2'-deoxyuridine (bmedu), (+ )-trans( sr, 6r)-s-bromo-s-ethyl-6-ethoxy-s, 6-deoxyuridine (beedu), (+ )-trans-(sr, 6r)-5-bromo-5-ethyl-6-ethoxy -s, 6-dihydro-s '-o-valeryl-2 ':.de...

The study investigated the corrosion-inhibitory properties of three synthetic triazole Mannich bases on C1018 carbon steel using various electrochemical techniques. inhibitors, namely 4-amino-2-[(4-methylpiperazin-1-yl)methyl]-5-(pyridin-4-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione (4MPT), 4-amino-2-[(piperidin-1-yl)methyl]-5-(pyridin-4-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione (PPT) and 4-ami...