A flow injection spectrophotometric method is proposed for the determination of bromoxynil herbicide. Bromoxynil was hydrolyzed with HCl and the resulting product, 3,5-dibromo-4-hydroxyaniline, was diazotized with nitrite and coupled with aniline. The absorbance of the azo dye was measured at 500 nm. The conditions were optimized for diazotization using FIA. The range of linearity was found to ...

A new method for the synthesis of allyl aromatic compounds not involving any metal-containing reagent or catalyst has been developed. Arylamines substituted with a large number of different substituents were converted via diazotizative deamination with tert-butyl nitrite in allyl bromide and acetonitrile to the corresponding allyl aromatic compounds. The allylation reaction was found to be suit...

A convenient, rapid, and one-pot method for the synthesis of azo dyes has been developed. In this protocol, diazotization reagent (ArN2+ -CrO3–SiO2) was prepared via grinding of aromatic amines, NaNO2, wet SiO2 and nano silica chromic acid (Nano-SCA) without solvent at room temperature. The obtained diazotization reagent was suff...

A convenient, rapid, and one-pot method for the synthesis of azo dyes has been developed. In this protocol, diazotization reagent (ArN2+ -CrO3–SiO2) was prepared via grinding of aromatic amines, NaNO2, wet SiO2 and nano silica chromic acid (Nano-SCA) without solvent at room temperature. The obtained diazotization reagent was suff...

An one-pot method has been developed for the synthesis of azo dyes via sequential diazotization–diazo coupling of aromatic amines with coupling agents at room temperature in the presence of Bi(NO3)3. 5H2O. Short reaction times, high yields, a clean process, simple methodology, easy work-up and green ‎conditions are advantages of this protocol.‎

A simple and sensitive spectrophotometric method for the determination of nitrogen dioxide in air and nitrite in water, soil, some analytical grade chemicals and tooth paste has been developed. Nitrogen dioxide in air is fixed as nitrite ion in alkaline sodium arsenite or triethanolamine absorber solution. The method is based on the reaction of nitrite in aqueous medium with known excess of Neu...

a convenient, one-pot method for the synthesis of diazonium salt has been developed by the sequential diazotization of aromatic amines with nano2, polymer- supported periodic acid (ppia) and 2-naphthole under solvent-free conditions at room temperature. by using this method, several types of aromatic amine, containing electron-withdrawing and electron-donating groups, were rapidly converted to ...

Alkylthio benzene derivatives were effectively synthesized by simultaneous diazotization of aromatic amines and nucleophilic displacement. The method is fairly general proceeds in moderate yields. Product yields comparable regardless steric hindrance the thiol or functional group present starting material. newly developed procedure allowed for incorporation a tertiary alkylthio group, which can...