Four polymerizable α-phosphonooxy phosphonic acids 7a, 7b, 9 and 16 were synthesized in seven steps. They were characterized by 1H, 13C and 31P NMR spectroscopy and by high-resolution mass spectroscopy. The copolymerization of acidic monomers 7a, 7b, 9 and 16 with 2-hydroxyethyl methacrylate was studied using a differential scanning calorimeter. Due to the presence of two acidic groups, those m...

OBJECTIVES Polymerized dental resin materials release residual monomers that may interact with pulp tissues. We hypothesized that dental adhesives might cause cytotoxicity in pulp cells via the generation of reactive oxygen species (ROS), which may also contribute to genotoxic effects in vitro. METHODS For cytotoxicity testing, transformed human pulp-derived cells were exposed to extracts of ...

STATEMENT OF PROBLEM One of the main problems posed by complete dentures is retention and stability. In order to solve this problem, dentists and the dental industry for a long time have attempted to improve denture adhesion by developing a range of "glues" of highly varied composition and efficacy. PURPOSE The present in vivo clinical study evaluates whether the adhesives used to improve com...

Antibacterial bonding agents and composites containing dimethylaminododecyl methacrylate (DMADDM) have been recently developed. The objectives of this study were to investigate the antibacterial effect of novel adhesives containing different mass fractions of DMADDM on Streptococcus mutans (S. mutans) biofilm at different developmental stages. Different mass fractions of DMADDM were incorporate...

The use of metals in dentistry has great therapeutic advantages in many fields of dentistry, such as orthodontics, prostheses, conservative dentistry since its origins and more recently implantology [2]. Likewise, metals can be used on numerous and varied substrates: enamel, dentin, ceramics, resins or other metals [1]. Examples of adhesion of enamel or dentin to metals, orthodontic bands and b...

Acrylic polymers have broad applications in the manufacture of paints and paper coatings, emulsion adhesives, plastics, lighting, glass replacements, personal care products and even dental fillings. However, acrylic acid and some acrylate oligomers and monomers adversely affect human health as eye and skin irritants. Exposure to monomers occurs primarily in the workplace via inhalation and derm...

OBJECTIVES The paper gives an overview on the components and the polymer chemical aspects of currently used self-etching enamel-dentin primers/adhesives. In addition, the contribution of new adhesives monomers and cross-linkers exhibiting enhanced hydrolytic stability than methacrylates to improve the performance of single-bottle adhesives is discussed. SOURCES Information from original scien...

Objective: The bonding adhesive holds the composite filling to the residual tooth, creating a chain cross-–link during the photo polymerization process. In this article we will be discussing the polymerization process under a thermodynamic viewpoint between amorphous structures of the dental market adhesives, the hybrid layer of the residual tooth and the white polymers filling. The thermodynam...

There has been dramatic progression in the adhesion of dental adhesives and resins to enamel and dentin in the 40 years since Buonocore1 introduced the technique of etching enamel with phosphoric acid to improve adhesion to enamel. The first dental adhesives bonded resins to enamel only, with little or no dentin adhesion. Subsequent generations have dramatically improved bond strength to dentin...