The engineering of molecular catalysts in homogeneous catalysis enables new catalytic modes, which leads to efficient synthetic transformations. In this regard, the design ligands for transition metal has played a major role. catalysed reactions, olefins can serve as steering by tuning electronic and steric nature centre. Here we report unstrained olefin that bear P or S coordination site use P...

Maleic anhydride (MAN) copolymers with methyl methacrylate(MMA), ethyl methacrylate(EMA), methyl acrylate(MA), ethyl acrylate (EA) and buthyl acrylate (BA) ( in a 1:1 mole ratio) were synthesized by free radical polymerizations method under vacuum -azobis(isobutironitrile)(AIBN) as an initiator of reaction at 701C. The copolymer compositions were determined using related 1H NMR spectra techni...

the studies report the synthesis of novel graft copolymer of oatmeal. polymethyl methacrylate grafting was carried out on oatmeal backbone via ‘microwave assisted’ approach. the graft copolymers were optimized by varying monomer and can concentration. the synthesized graft copolymers were characterized by intrinsic viscosity, ftir, tga, sem, elemental analysis, number average molecular weight a...

4-chloromethyl styrene (cms) was copolymerized with different monomers such as methyl methacrylate (mma), methyl acrylate (ma), 2-ethylhexyl acrylate (eha) by free radical polymerization method at 70 ±1°c using a,a'-azobis(isobutyronitrile) (aibn) as an initiator. the copolymer compositions were obtained using related 1hnmr spectra and the polydispersity of the copolymers were determined using ...

In this study, poly carbonate (PC) and poly (ethylene terephthalate) (PET) were reactive melt-blended under two different conditions to produce PC/PET copolymers. For each condition, samples were taken at specified mixing times representative a specific structure of copolymers and each one employed to physically compatibilize a PC/PET blend with a fixed composition. Reactive blending and copoly...

Recent trends in the development of microfluidic and biodiagnostic chips favor polymer materials over glass, primarily for optical and economical reasons. Therefore, existing chemical methods to prepare biomolecule microarrays on glass slides have to be adapted or replaced in order to suit polymer substrates. Here we present a strategy to immobilize DNA and antibodies on cyclic polyolefin slide...

Linear–dendrite copolymers containing hyper branched poly(citric acid) and linear poly(ethylene glycol) blocks PCA–PEG–PCA are promising nonmaterial to use  in nanomedicine. To investigate their potential application in biological systems (especially for drug carries) ONIOM2 calculations were applied to study the nature of particular interactions between drug and the polymeric nanoparticle...

We report a cost-efficient and easy to implement process for fabricating microfluidic reactors in thermoplastic materials. The method includes (i) the fabrication of an imprint template (master), which consists of a photoresist deposited on a metal plate; (ii) the thermoembossing of the reactor features into polymer sheets; (iii) the activation of the embossed and planar thermoplastic surfaces;...

The new highly active supported vanadium-magnesium catalyst (VMC) has been studied in α-olefin (1-butene, 1-hexene)/ ethylene copolymerization in the presence of hydrogen. Data on the effect of α-olefin/ethylene ratio in copolymerization on the content of branchings in copolymers, kinetic profile, copolymer yield, molecular weight and molecular weight distribution of copolymers have been obtain...