نتایج جستجو برای: cyanoacrylic

تعداد نتایج: 58  

Journal: :Sakarya University Journal of Science 2021

Two new metal-free organic dyes in D-π-A structure, containing a quinoline π-bridge and malononitrile (4a) cyanoacrylic acid (4b) as acceptors, were synthesized for the first time to apply dye-sensitized solar cell (DSSC). The structures of these compounds elucidated by FT-IR, 1H NMR, 13C NMR techniques. photophysical photovoltaic properties obtained investigated compared current density–voltag...

2014
Christopher Koenigsmann Bradley J. Brennan Christian F. A. Negre Matthieu Koepf Alec C. Durrell Rebecca L. Milot Victor S. Batista Gary W. Brudvig Robert H. Crabtree Charles A. Schmuttenmaer Teresa S. Ripolles Jose A. Torre Juan Bisquert

An efficient synthetic protocol to functionalize the cyanoacrylic acid anchoring group of commercially available MK-2 dye with a highly water-stable hydroxamate anchoring group is described. Extensive characterization of this hydroxamate-modified dye (MK-2HA) reveals that the modification does not affect its favorable optoelectronic properties. Dye-sensitized solar cells (DSSCs) prepared with t...

2014
Christoph K Winkler Dorina Clay Nikolaus G Turrini Horst Lechner Wolfgang Kroutil Simon Davies Sebastien Debarge Pat O'Neill Jeremy Steflik Mike Karmilowicz John W Wong Kurt Faber

Asymmetric bioreduction of an (E)-β-cyano-2,4-dienoic acid derivative by ene-reductases allowed a shortened access to a precursor of pregabalin [(S)-3-(aminomethyl)-5-methylhexanoic acid] possessing the desired configuration in up to 94% conversion and >99% ee. Deuterium labelling studies showed that the nitrile moiety was the preferred activating/anchor group in the active site of the enzyme o...

In this paper we studied preparation of working films of dye-sensitized solar cells using screen printed method. The organic dye based on phenoltiazine with cyanoacrylic acid as the electron donor group utilized as photosensitizer. Fluorine-doped thin oxide FTO coated glass is transparent electrically conductive and ideal for use in dye-sensitized solar cells. FTO glass was coated by screen pri...

A.D. Khalaji

Two organic compounds (SC-23=(E)-2-Cyano-3-(2,3-dimethoxyphenyl) acrylic acid and SC-25=(E)-2-Cyano-3-(2,5-dimethoxyphenyl) acrylic acid) involving methoxy groups as the electron donor and cyanoacrylic acid group as the electron acceptor have been investigated for dye sensitized solar cells. They shows a short-circuit current density (Jsc) of 2.08 and 1.81 mA cm-2, an open circuit voltage (Voc)...

In this paper we used two free-metal organic dyes (dye 1 and dye 2) based on indigo and thioindigo with cyanoacrylic acid as the electron acceptor group. The proposed dyes were sensitized from naphalene as the starting material by standard reactions and characterized by different analytical techniques and UV-Visible spectroscopy after purification. Spectrophotometric measurements of the organic...

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