In this work, the solution-processed CH3NH3PbI3 perovskite/copper indium disulfide (CuInS2) planar heterojunction solar cells with Al2O3 as a scaffold were fabricated at a temperature as low as 250°C for the first time, in which the indium tin oxide (ITO)-coated glass instead of the fluorine-doped tin oxide (FTO)-coated glass was used as the light-incidence electrode and the solution-processed ...

2014 Novel methods for the material synthesis, crystal growth and film preparation of CuInS2 were developed, some of their properties were characterized. CuInS2 single crystals were grown by iodine vapour transport. The habit-planes were determined to be (112) and (110). The lattice parameters were determined to be a = 5.517 Å, c = 11.122 Å (tetragonal). The as-grown crystals were n-type with r...

In the present work, CuInS2 nanoparticles have been successfully synthesized by water-bath method with deionized water as solvent and thioglycolic acid as complexing agent at 80°C. The phase transition of CuInS2 from chalcopyrite to wurtzite was realized by adjusting the pH value of reaction solution. The emergence of Cu2S in the condition of higher pH value of reaction solution led to the form...

Here we explored the possibility of using CuInS2-based nanocrystals as colour converting materials for light-emitting applications. Using a mixture of red and green emissive CuInS2-based nanocrystals, we successfully fabricated high colour rendering white light-emitting diodes with surface mounted devices and high-power types. The devices exhibit improved luminous efficiency, high colour render...

Photoluminiscent (PL) cellulose aerogels of variable shape containing homogeneously dispersed and surface-immobilized alloyed (ZnS)x(CuInS2)1-x/ZnS (core/shell) quantum dots (QD) have been obtained by (1) dissolution of hardwood prehydrolysis kraft pulp in the ionic liquid 1-hexyl-3-methyl-1H-imidazolium chloride, (2) addition of a homogenous dispersion of quantum dots in the same solvent, (3) ...

Nearly monodisperse alloyed (CuInS2)x(ZnS)1-x nanocrystals with cubic and hexagonal phases were successfully synthesized for the first time, and the band gaps of these alloyed nanocrystals can be tuned in the broad range of 1.5 to 3.7 eV by changing the ratio of CuInS2 to ZnS.

Well-aligned ZnO nanorods were uniformly coated with a layer of CuInS2 nanoparticle photosensitizers using a tailored sequential pulsed electrodeposition. The formation of CuInS2-ZnO heterojunction with well-matched band energy alignment and the superior electron mobility in ZnO nanorods led to a remarkable 3.75 times improved photoelectrochemical performance of the electrode under visible ligh...

The capacity of fluorescent colloidal semiconductor nanocrystals for commercial application has led to the development of nanocrystals with nontoxic constituent elements as replacements for the currently available Cd- and Pb-containing systems. CuInS2 is a good candidate material because of its direct band gap in the near-infrared spectral region and large optical absorption coefficient. The te...

Heterojunction solar cells based on colloidal nanocrystals (NCs) have shown remarkable improvements in performance in the last decade, but this progress is limited to merely two materials, PbS and PbSe. However, solar cells based on other material systems such as copper-based compounds show lower power conversion efficiencies and much less effort has been made to develop a better understanding ...

CuInSe2 and CuInS2 form a continuous solid solution in which the optical bandgap varies from 1.0 to 1.55 eV [1]. By reacting CuInSe2 films in a flowing H2S/Ar atmosphere, the films can be completely converted to CuInS2 or converted to a graded CuIn(Se1-ySy)2 film, depending on processing conditions. A phenomenological model of the reaction/diffusion process is presented wherein H2S reacts with ...