We examined the structural properties of copper sulfide films as a function of the sulfurization time of 70-nm-thick Cu films. Copper sulfide films with various phases such as mixed metallic Cu-chalcocite, chalcocite, roxbyite, and covellite phases were formed with increasing sulfurization time. To evaluate the structural stability of various films, all the films were exposed to the ambient atm...

In this work, the parameters affecting the recovery of copper from the low-grade sulfide minerals of Sarcheshmeh Copper Mine were studied. A low-grade sulfide ore was used with a copper grade of 0.25%, which was about 28% of the mineral oxide, and the sulfide minerals made up the rest. Much more sulfide minerals were found to be pyrite and most of the gangue minerals were quartz, anorthite, bio...

The aim of this work was to characterize copper ferrite nanoparticles synthesized via solvothermal method and to investigate the effects of ultrasonic waves on the synthesis efficiency. Crystal structure, functional groups, microstructure, particle size, magnetic properties, specific surface area, porosity distribution and photocatalytic activity of the synthesized nanoparticles were also inves...

Single-crystalline TiOF(2) crystals with cubical morphology were prepared via a facile solvothermal method and their transformation to anatase TiO(2) under different calcination conditions such as pure argon, moist argon and pure hydrogen sulfide (H(2)S) was explored by using XRD/Raman/UV-Vis/SEM/TEM/SAED. The non-metal sulfur doping was successfully fulfilled and the doped TiO(2) microcubes sh...

Scientists from the U.S. Geological Survey are evaluating the potential for undiscovered sulfide deposits containing varying amounts of nickel, copper, platinumgroup metals, and cobalt in the Lake Superior region as part of an ongoing effort to assess the mineral potential of the United States. Similarities between rocks of the Midcontinent rift and rocks that host the Voisey Bay nickel-copper-...

Recently helical nanostructures such as nanosprings and nanocoils have drawn great interests in nanotechnology, due to their unique morphologies and physical properties, and they may be potential building blocks in sorts of electromechanical, magnetic, photoelectronic and plasmonic devices at micro/nanoscales. In this report, multi-turns copper nanocoils were synthesized through a modified solv...

Hydrogen sulfide (H2S) impairs mitochondrial respiration by potently inhibiting the heme-copper cytochrome c oxidase. Since many prokaryotes, including Escherichia (E.) coli, generate H2S and encounter high H2S levels particularly in the human gut, herein we tested whether bacteria can sustain sulfide-resistant O2-dependent respiration. E. coli has three respiratory oxidases, the cyanide-sensit...

Control over the doping density in copper sulfide nanocrystals is of great importance and determines its use in optoelectronic applications such as NIR optical switches and photovoltaic devices. Here, we demonstrate that we can reversibly control the hole carrier density (varying from >1022 cm-3 to intrinsic) in copper sulfide nanocrystals by electrochemical methods. We can control the type of ...

The PAQUES Bio Systems’ core technology, marketed under the name THIOPAQ, consists of various high-rate biological processes for metal-sulfur-water systems, complemented with common solid/liquid and gas separation steps. Sulfur species are converted to sulfide, which is a valuable component as it can be used for metals reduction and precipitation. Selective recovery of valuable metals can be em...