The use of metal complexes to achieve a conductive molecular junction with a special focus on organometallics is overviewed and illustrated with representative examples. The prospects offered by such compounds owing to their specific properties are discussed.

Langmuir and Langmuir-Blodgett (LB) films of a great variety of molecular metal complexes with interesting magnetic or optical properties have been prepared in the last few years. Some of the results obtained by our group and others are summarized in this article.

For metal-based compounds, the ground- and excited-state dipole moments and the difference thereof are, for the first time, obtained both experimentally and theoretically using solvatochromic equations and DFT/B3LYP/QZVP calculations. The approach is suggested to be promising and easily accessible, and can be universal to elucidate the electronic properties of metal-based compounds.

objective in this article, a motor skill disorder called developmental coordination disorder (dcd), that is usually first diagnosed during childhood, is explained and discussed. in the year 1987, dcd was formally recognized as a distinct disorder in children by the american psychiatric association  (apa). dcd is a generalized term for the children who have some degrees of impairment in the deve...

the stereochemistry of the actinide elements has recently undergone considerable development and a wide variety of coordination numbers and geometries have been observed. this structural versatility arises from the lack of strong crystal field effects for the 5f-electronic configurations as well as from the large ionic radii of these metal ions, which change markedly with oxidation number, or a...