by redox-active metal chelates has recently been reported. Rana and Meares demonstrated that an EDTA–Fe derivative, covalently attached to a cysteine residue of the protein, can mediate cleavage of the protein backbone in a conformationdependent manner. A different EDTA–Fe derivative attached to a protein has been described for the affinity cleavage of proteins. In these cases, cleavage of the ...

A high-performance liquid chromatography-electrospray ionization/mass spectrometry (time of flight) method has been developed for the simultaneous determination of synthetic Fe(III)-chelates used as fertilizers. Analytes included the seven major Fe(III)-chelates used in agriculture, Fe(III)-EDTA, Fe(III)-DTPA, Fe(III)-HEDTA, Fe(III)-CDTA, Fe(III)-o,oEDDHA, Fe(III)-o,pEDDHA, and Fe(III)-EDDHMA, ...

Chelating is the chemical process by which a mineral (iron, cobalt, copper, zinc, and manganese) is combined with a mixture of amino acids and peptides. The resulting substances are known as chelates. Another descriptive term, proteinates, refers to the amino acid bond. These chelated minerals are thought to be more digestible than nonchelated forms. In other words, chelation makes the minerals...

4-Nitrobenzoylsemicarbazone-1-phenyl-3-methyl-2-pyrazolin-5-one (NBMP-SC) was prepared and its metal chelates of Cu,Ni,Co,Mn,Fe,Fe,Cr,UO2 and OV were prepared. The ligands and its chelates were characterized by elemental analysis, Metal: ligand (M:L) stoichiometry, IR-electronic spectral studies and magnetic properties. The compounds also were screened for their antimicrobial activity.

chelating is the chemical process by which a mineral (iron, cobalt, copper, zinc, and manganese) is combined with a mixture of amino acids and peptides. the resulting substances are known as chelates. another descriptive term, proteinates, refers to the amino acid bond. these chelated minerals are thought to be more digestible than nonchelated forms. in other words, chelation makes the minerals...

the kinetics of the de complexation by hydroxyl ions of some pervanadyl, molybdate and tungstate amionocarboxylate complexes have been studied spectrophotometrically by means of a stopped flow technique. the chelate groups used were the iminodiacetic acid (ida), ethylenediarnine-n,n' -diacetic acid (edda), nitrilotriacetic acid (nta) and ethylene diamine-n,n,n' ,n'-tetraacetic ac...

Water binding to several Mg(2+) chelates, ethylenediamine, ethylenediamine-N,N'-diacetate, porphyrin, chlorophyll a and bacteriochlorophyll a, to form five- and six-coordinate complexes is studied by means of density functional theory. The results obtained for magnesium chelates are compared with the properties of the respective aqua complexes and the influence of the permittivity of environmen...

Coordination exchange processes tend to dominate the solution state behaviour of lanthanide chelates and generally prohibit the study of small conformational changes. In this article we take advantage of coordinatively rigid Eu(3+) chelates to examine the small conformational changes that occur in these chelates as water dissociatively exchanges in and out of the inner coordination sphere. The ...