The reaction of nano-cellulose and antimony pentachloridein dichloromethane gave nano-cellulose-SbCl5. Also nano-cellulose-SbCl5 has beencharacterized by energy dispersive X-ray spectroscopy(EDX), scanning electron microscopy (SEM)and Fourier transform infrared spectroscopy(FTIR).Nano-cellulose-SbCl5has been applied as a nano-catalyst for synthesis of pyrano[2,3-d]pyrimidines from the simple on...

-l, Carbon-14 labeled cellulose was fed to rock ptarmigan to provide evidence of cellulose digestion and metabolism. Digestibility of cellulose and energy metabolized by ptarmigan fed a diet of 6 and 30';0 cellulose were determined by a feeding trial. 2. Recovery of t'~CO2 in expired gases from ptarmigan fed t*C labeled cellulose demonstrates the digestion and metabolism of cellulose by gut mic...

An earlier safety assessment of several cellulose polymers has been expanded to include cellulose itself and other cellulose polymers used in cosmetics. In general, these ingredients are modified cellulose polymers formed by reaction with the free hydroxyl groups in cellulose. The number of hydroxyl groups reacting, as well as the nature of the substitute group, largely determine the physical p...

X-ray and neutron fiber diffraction has been used to study cellulose as it is converted from its naturally occurring crystal phase, cellulose I, to an activated crystal phase, cellulose IIII, by ammonia treatment. The detailed crystal structures determined for cellulose Iβ, an intermediate ammonia-cellulose I complex, and cellulose IIII, reveal a structural transition pathway: hydrogen bonded s...

New bionanocomposite proton exchange membranes were prepared from sulfonated polybenzimidazole (s-PBI) and various amounts of sulfonated ZnO/cellulose nanohybrids (ZnO/cellulose-SO3H). The use of ZnO/cellulose-SO3H compensates for the decrease in ion exchange capacity of membranes observed when non-sulfonated nano-fillers are utilized. The strong –SO3H/–SO<su...

The amalgamation of polymer and pharmaceutical sciences led to the introduction of polymer in the design and development of drug delivery systems. Polymeric delivery systems are mainly intended to achieve controlled or sustained drug delivery. Polysaccharides fabricated into hydrophilic matrices remain popular biomaterials for controlled-release dosage forms and the most abundant naturally occu...

Shape-persistent and tough cellulose hydrogels were fabricated by a stepwise solvent exchange from a homogeneous ionic liquid solution of cellulose exposure to methanol vapor. The cellulose hydrogels maintain their shapes under changing temperature, pH, and solvents. The micrometer-scale patterns on the mold were precisely transferred onto the surface of cellulose hydrogels. We also succeeded i...

The interaction between cellulase enzymes and their substrates is of central importance to several technological and scientific challenges. Here we report that the binding of cellulose binding modules (CBM) from Trichoderma reesei cellulases Cel6A and Cel7A show a major difference in how they interact with substrates originating from wood compared to bacterial cellulose. We found that the CBM f...