Thermal analysis of acrylonitrile/acrylic acid P(AN/AA) copolymer films containing 5%, 10% and 20% acrylic acid dendrigrafted with citric acid (CA) is examined using differential scanning calorimetry (DSC) with various heating rates, thermogravimetry (TGA) and derivative thermogravimetric analysis (DTG). Also, the effect of carboxylic acid on thermal stabilization of the P(AN/AA) copolymers, wh...

Cherry cake berries, which is a waste of liquor production, contain biologically active substances, including lipids, are not extracted by ethanol in the main production. Supercritical carbon dioxide good extractant for such compounds. By method full factor experiment using rotatable uniform-plan second order, process optimization extraction cherry oil from processed berries supercritical fluid...

The extraction equilibrium of indium(III) from a nitric acid solution using di(2-ethylhexyl) phosphoric acid (D2EHPA) as an acidic extractant of organophosphorus compounds dissolved in kerosene was studied. By graphical and numerical analysis, the compositions of indium-D2EHPA complexes in organic phase and stoichiometry of the extraction reaction were examined. Nitric acid solutions with vario...

A method for the determination of biomarker fatty acids (C12–C28) in soils' lipids that involves their extraction, chemical modification and gas chromatographic detection with a flame ionization detector (GC-FID) has been developed. This methodology allows to evaluate content free soil (not bound lipids). The extraction from was optimized according following parameters: type extractant, ratio m...

aqueous polyurethane dispersions (puds) have recently emerged as important alternatives to their solvent-based counterparts for various applications due to increasing health and environmental awareness (green chemistry). anionic polyester-polyurethane dispersions were synthesized by three steps. in the first step, macromonomer diisocyanate having carboxylic acid was prepared by isophorone diiso...

The potential use of synergistic mixtures of reagents for the solvent extraction of nickel (and cobalt) from lateritic leach liquors was pointed out in the early 1980s by Grinstead, who used dinonylnaphthalene sulphonic acid in conjunction with some 2-pyridyl compounds for the recovery of these metals from slightly acidic solutions1,2. Shortly thereafter, studies at Mintek revealed marked syner...

Ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), and other synthetic polycarboxylic acids have been shown to possess substantial capacity as washing agents of heavy metal-polluted soils, but they are environmentally problematic. Therefore, a sample of natural soluble humic substances (HS) was tested as a possible substitute. The efficiency of HS to extract cadmium (Cd), copp...

This study aimed to synthesize quinolinone derivatives and investigate their cytotoxic activity. The compound 1-azacoumarin-3-carboxylic acid (2-oxo-1H-quinoline-3-carboxylic acid) was obtained via the cyclocondensation of 2-hydroxybenzaldehyde with diethyl malonate in base catalyst give ethyl coumarin-3-carboxylate, followed by ammonolysis ester (ethyl coumarin-3-carboxylate) ammonia presence ...