2014 In substoichiometric transition metal carbides and nitrides crystallizing with the NaCl structure, the vacancies, which appear on the metalloid FCC lattice only, may order under some conditions. The corresponding long range ordered phases are analogous to those predicted, for FCC substitutional alloys, by theoretical calculations using pair interactions limited to first and second neighbou...

The ASTM F-75 (Co-28%Cr-6%Mo) is widely used as a biocompatible alloy in medicine for manufacturing implants. In this study, effect of mold preheating on the as-cast microstructure of the alloy was investigated using the solid investment casting process. Several mold preheating temperatures of 550, 700, 850 and 1000 °C were selected at the same melt superheat. The samples were characterized by ...

In this study, double loop electrochemical potentiokinetic reactivation (DLEPR) test was applied to determine the degree of sensitization in 316L type stainless steel, where obtained results were correlated with revealed microstructures after oxalic acid test and weight loss measurements of Streicher and Huey acid tests. Best agreement was provided with test parameters which are 1 M H2SO4 and 0...

In order to optimize the hot forming process of tool steels, further improvement of flow stress prediction and additional knowledge on hot deformability, especially at lower and upper limits of the hot working range, are required. The hot working ranges for these steels are very narrow as a consequence of the role of alloying elements, which form carbides. Carbides improve tool steel’s hardenab...

The aim of this work was to characterize the microstructure of the as-cast Haynes® 282® alloy. Observations and analyses were carried out using techniques such as X-ray diffraction (XRD), light microscopy (LM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray spectroscopy (EDS), wave length dispersive X-ray spectroscopy (WDS), auger electron spectroscopy (AES) a...

The microstructural and mechanical properties of the hard phases in CoCrMo prosthetic alloys in both cast and wrought conditions were examined using transmission electron microscopy and nanoindentation. Besides the known carbides of M(23)C(6)-type (M=Cr, Mo, Co) and M(6)C-type which are formed by either eutectic solidification or precipitation, a new mixed-phase hard constituent has been found ...

Transition metal nitrides, carbides and borides have a high potential for industrial applications as they not only have a high melting point but are generally harder and less compressible than the pure metals. Here we summarize recent advances in the synthesis of binary transition metal nitrides, carbides and borides focusing on the reaction of the elements at extreme conditions generated withi...

Thanks to their refractoriness, carbides are sensed as fuel coating for the IV generation of reactors. Among those studied, the Ti3SiC2 ternary compound can be distinguished for its noteworthy mechanical properties: the nanolamellar structure imparts to this material some softness as well as better toughness than other classical carbides such as SiC or TiC. However, under irradiation, its behav...

Transition metal carbides and nitrides have received a large amount of attention in chemistry and materials science due to their interesting properties and potential to substitute precious metal catalysts. Earthabundant early transition metal carbides and nitrides were the primary focus of many efforts, while late transition metal alternatives are less explored. This brief review discusses rece...

Low carbon ferritic steel alloyed with Ti, Mo and Cu was hot rolled and interrupt cooled to produce nano-sized precipitates of copper and (Ti,Mo)C carbides. The steel had a tensile strength of 840 MPa, an increase in yield strength of 380 MPa over that of the plain carbon steel and reasonable ductility. Transmission electron microscopy and small angle neutron scattering were used to characteriz...