Metal hydride applications span a wide variety of tech! nologies\ e[g[\ energy conversion\ chemical compressors and hydrogen storage[ A knowledge of heat and mass transfer in a metal hydride reactor during the absorption and desorption of hydrogen is important for performance optimization of the reactor[ One of the key requirements in the design of metal hydride bed is the enhancement of the e}...

Attempts to generate a proposed rhodium hydride catalytic intermediate instead resulted in isolation of (Cp*H)Rh(bpy)Cl (1), a pentamethylcyclopentadiene complex, formed by C-H bond-forming reductive elimination from the fleeting rhodium hydride. The hydride transfer ability of diene 1 was explored through thermochemistry and hydride transfer reactions, including the reduction of NAD(+).

The hydridic character of octahedral metal hydride complexes of groups VI, VII and VIII has been systematically studied using molecular electrostatic potential (MESP) topography. The absolute minimum of MESP at the hydride ligand (Vmin) and the MESP value at the hydride nucleus (VH) are found to be very good measures of the hydridic character of the hydride ligand. The increasing/decreasing ele...

ABSTRACT: Using agricultural waste is one of the best ways to reduce the costs and the environmental pollution. Button mushroom´s stipe is a cheap by-product that is rich in nutrients for human nutrition. The purpose of this study is to compare the nutritional value of cap and stipe of button mushroom (Agaricus bisporus). The caps were separated from the stipes after harvesting and parameters s...

abstract: using agricultural waste is one of the best ways to reduce the costs and the environmental pollution. button mushroom´s stipe is a cheap by-product that is rich in nutrients for human nutrition. the purpose of this study is to compare the nutritional value of cap and stipe of button mushroom (agaricus bisporus). the caps were separated from the stipes after harvesting and parameters s...

Aluminum hydride, a very interesting and valuable reducing agent, has been widely used in numerous applications in organic syntheses. Jorgenson first reported the comparison in the reducing properties between lithium aluminum hydride and aluminum hydride on the reduction of cinnamaldehyde, and Brown and Yoon reported a systematic study on the reducing properties of aluminum hydride in THF. Fina...

The dissociative sticking probability for H2 on Pd films supported on sputtered Highly Ordered Pyrolytic Graphite (HOPG) has been derived from measurements of the rate of the H–D exchange reaction at 1 bar. The sticking probability for H2, S, is higher on Pd hydride than on Pd (a factor of 1.4 at 140 C), but the apparent desorption energy derived from S is the same on Pd and Pd hydride within t...

The sequential treatment of Lewis acids with N,N'-bidentate ligands and thereafter with ButLi has afforded a series of hydride-encapsulating alkali metal polyhedra. While the use of Me3Al in conjunction with Ph(2-C5H4N)NH gives Ph(2-C5H4N)NAlMe2 and this reacts with MeLi in thf to yield the simple 'ate complex Ph(2-C5H4N)NAlMe3Li.thf, the employment of an organolithium substrate capable of beta...

Calcium borohydride (Ca(BH4)2) is a complex hydride that has been less investigated compared to its lighter counterpart, magnesium borohydride. While offering slightly lower hydrogen storage capacity (11.5 wt% theoretical maximum, 9.6 under actual dehydrogenation conditions), there are many improvement avenues for maximizing the reversible have explored recently, from DFT calculations and polym...