A series of sodium borosilicate glasses were synthesized with KReO4 or Re2O7, to 10,000 ppm (1 mass%) target Re, to assess effects of large concentrations of rhenium on glass structure and fto estimate solubility of Tc, a radioactive component in low active waste nuclear glasses. Rhenium was used as a surrogate for Tc for laboratory testing, due to similarities in chemistry, ionic size, and red...

Deep reactive ion etching (DRIE) of borosilicate glass and profile control of an etched groove are reported. DRIE was carried out using an anodically bonded silicon wafer as an etching mask. We controlled the groove profile, namely improving its sidewall angle, by removing excessively thick polymer film produced by carbonfluoride etching gases during DRIE. Two fabrication processes were experim...

Deep reactive ion etching (DRIE) of borosilicate glass and profile control of an etched groove are reported. DRIE was carried out using an anodically bonded silicon wafer as an etching mask. We controlled the groove profile, namely improving its sidewall angle, by removing excessively thick polymer film produced by carbonfluoride etching gases during DRIE. Two fabrication processes were experim...

We present data that illustrate some advantages of Cherenkov counting for the radioassay of 90Y in the dry state and provide recommendations concerning sample counting geometry. Slightly higher detection efficiencies and figures-of-merit were obtained when counting 90Y in the dry state in polyethylene plastic counting vials compared to the counting of 90Y in 20 ml of water in borosilicate glass...

The effect of helium implantation fluences in French nuclear borosilicate glass on He bubble nucleation and growth mechanisms was characterised using in-situ TEM experiments. Observations of implanted glass at 143K indicate that a helium concentration of around 3 at.% is required to nucleate a significant density of nanosized bubbles. He bubble growth is observed for He concentration higher tha...

The structures of glasses prepared by melting mixtures of alkali borosilicate glass and silicon nitride powders and by ammonolysis of porous borosilicate gels were studied using Fourier transform infrared spectroscopy and combustion analysis. Whereas there was little evidence of nitride bond formation in the melt prepared glasses, Si-N and B-N bonding were observed in the gel-derlved glasses. I...

The direct peptide reactivity assay (DPRA) is a validated method for in vitro assessment of the skin sensitization potential of chemicals. In the present work, we describe a peptide reactivity assay using 96-well plate format and systematically identified the optimal assay conditions for accurate and reproducible classification of chemicals with known sensitizing capacity. The aim of the resear...