Boron nitride nanotubes (BNNTs) are of intense scientific interest due to their unique physiochemical properties and prospective applications in various nanotechnologies, particularly nanobiomedicine. A critical problem hamper‐ ing the application processing of BNNTs is the outer sidewall functionalization, which is primarily acquired to lead BNNTs dispersible in various solvents. Furthermore, ...

The effect of uni-axial strain on the electronic properties of (8,0) zigzag and (5,5) armchair boron nitride nanotubes (BNNT) is addressed by density functional theory calculation. The stress-strain profiles indicate that these two BNNTS of differing types display very similar mechanical properties, but there are variations in HOMO-LUMO gaps at different strains, indicating that the electronic ...

Bias dependent scanning tunneling microscopy and scanning tunneling spectroscopy have been used to characterize the influence of transverse electric fields on the electronic properties of boron-nitride nanotubes (BNNTs). We find experimental evidence for the theoretically predicted giant Stark effect. The observed giant Stark effect significantly reduces the band gap of BNNTs and thus greatly e...

Boron nitride nanotubes (BNNTs) [ 1,2 ] and boron nitride nanosheets (BNNSs) [ 3 ] have gained increasing attention for their structural similarity to carbon nanotubes (CNTs) and graphene, respectively. These BN nanostructures are wide-bandgap materials ( ∼ 6 eV), and their electronic properties are different from those of CNTs and graphene. In addition, BNNTs and BNNSs offer intriguing propert...

Multiand double-walled boron nitride nanotubes (BNNTs) have been synthesized with the aid of a floating nickel catalyst via the catalytic chemical vapor deposition (CCVD) of either the amineborane borazine (B3N3H6) or the polyhedral-borane decaborane (B10H14) molecular precursors in ammonia atmospheres. Both sets of BNNTs were crystalline with highly ordered structures. The BNNTs grown at 1200 ...

Superhydrophobic surfaces are attractive as self-cleaning protective coatings in harsh environments with extreme temperatures and pH levels. Hexagonal phase boron nitride (h-BN) films are promising protective coatings due to their extraordinary chemical and thermal stability. However, their high surface energy makes them hydrophilic and thus not applicable as water repelling coatings. Our recen...

The electrical properties of boron nitride (BN) nanostructures, particularly BN nanotubes (NTs), have been studied less in comparison to the counterpart carbon nanotubes. The present work investigates the field emission (FE) behavior of BNNTs under multiple cycles of FE experiments and demonstrates a strain-engineering pathway to tune the electronic properties of BNNTs. The electrical probing o...

We have synthesized boron nitride nanotubes (BNNTs) in an arc in presence of boron and nitrogen species only, without transition metals. We find that BNNTs are often attached to pure boron nanoparticles, suggesting that root-growth is a likely mechanism for their formation. To gain further insight into this process we have studied key mechanisms for root growth of BNNTs on the surface of a liqu...

Selective growth of boron nitride nanotubes (BNNTs) was demonstrated by plasma-enhanced pulsed laser deposition (PE-PLD). Although PLD is a physical vapor deposition technique for the growth of boron nitride (BN) thin films, ion sputtering induced by the plasma can eliminate the formation of BN thin films and lead to the so-called total resputtering region, in which, a pure phase of BNNTs can b...

Effective growth of multiwalled boron nitride nanotubes (BNNTs) has been obtained by thermal chemical vapor deposition (CVD). This is achieved by a growth vapor trapping approach as guided by the theory of nucleation. Our results enable the growth of BNNTs in a conventional horizontal tube furnace within an hour at 1200 °C. We found that these BNNTs have an absorption band edge of 5.9 eV, appro...