A series of polyether-based diblock copolymers were synthesized by sequential organocatalytic ring-opening polymerization (ROP) either hexene oxide (HO) or octene (OO) as the first monomer with propylene (PO) second monomer. In addition, one triblock terpolymer OO, PO, and styrene (SO) was following same method. The ROP catalyzed triethyl borane (TEB)/(phosphazene base t-BuP2) eicosanol initiat...

Electrically-induced behaviuor was compared in the non-stretched and uniaxially stretched poly(vinylidene fluoride-trifluoroethylenechlorofluoroethylene) terpolymer a member of the relaxor polymer family that exhibits fast response speeds, a giant electrostriction, high electric energy density and a large electrocaloric effect. Although the temperature dependence of the low-field dielectric con...

The present paper deals with the synthesis of terpolymer films of MMA-STY-AN and their physical properties were studied. The films were translucent, brittle and light yellow in colour. The films were found water permeable. The films were soluble in most of non polar solvents. The softening range of alloy films was found in between 89–119 0C. The specific conductance of terpolymer films was foun...

Block copolymers have been proposed for self-assembled nanolithography because they can spontaneously form well-ordered nanoscale periodic patterns of lines or dots in a rapid, low-cost process. By templating the selfassembly, patterns of increasing complexity can be generated, for example arrays of lines with bends or junctions. This offers the possibility of using a sparse template, written b...

By combining three mutually immiscible polymeric components in a mixed-arm star block terpolymer architecture, we have observed the formation of a previously unknown class of multicompartment micelles in dilute aqueous solution. Connection of water-soluble poly(ethylene oxide) and two hydrophobic but immiscible components (a polymeric hydrocarbon and a perfluorinated polyether) at a common junc...

We report the first use of a block terpolymer for the synthesis of three-component nanocomposites. Here, the use of three chemically distinct polymer blocks enabled control over each of the three final components: partially graphitic carbon, crystalline transition metal oxide, and porosity. Tuning of the individual block lengths and block fractions resulted in control over the three components....

Superconductors with periodically ordered mesoporous structures are expected to have properties very different from those of their bulk counterparts. Systematic studies of such phenomena to date are sparse, however, because of a lack of versatile synthetic approaches to such materials. We demonstrate the formation of three-dimensionally continuous gyroidal mesoporous niobium nitride (NbN) super...

Terpolymers of L-lactide, D,L-lactide and trimethylene carbonate (TMC) were synthesized via the ring-opening polymerization reaction for cyclic monomers using stannous octoate as the initiator at a ratio of ~0.05 mol% (monomers/(SnOct) 2 ). Synthesis was done at 130 °C for 48 h. The inclusion of TMC, an aliphatic elastomeric polycarbonate, alongside polymer chain segments containing L-lactide a...

The copolymerization of poly(3-hydroxybutyrate) (PHB) is a promising trend in bioengineering to improve biomedical properties, e.g. biocompatibility, of this biodegradable polymer. We used strain Azotobacter chroococcum 7B, an effective producer of PHB, for biosynthesis of not only homopolymer and its main copolymer, poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHB-HV), but also novel terpolym...

Biodegradable amphiphilic poly (ethylene glycol) (PEG) based ether-anhydride terpolymer, consisting of PEG, 1, 3-bis (p-carboxyphenoxy) propane (CPP) and sebacic acid (SA), namely PEG-CPP-SA terpolymer, was employed to self-assemble into micelles by adding water into a solution of the terpolymer in tetrahydrofuran (THF). The shape of polyanhydride micelles can be regulated by simply adjusting t...