Polyvinyledenefluoride–polystyrene (PVDF/PS) blend ultrafiltration membranes were prepared using phase inversion technique. Casting solutions were prepared with different compositions of polyvinylidene fluoride (PVDF) and polystyrene (PS) both in the presence and absence of the additive, polyvinylpyrolidone (PVP) using dimethylacetamide as solvent. The effects of compositions of PS and concentr...

Polymer electrolyte membrane (PEM) composed of polymer or blend is a vital element in PEM fuel cell that allows proton transport and serves as barrier between oxygen. Understanding the microscopic phase behavior blends very crucial to design alternative cost-effective proton-conducting materials. In this study, mesoscale morphologies Nafion/poly(1-vinyl-1,2,4-triazole) (Nafion-PVTri) Nafion/pol...

A  new  type  of  cation-exchange  nanocomposite  membranes  was prepared  by  in-situ  formation  of  ZnO  nanoparticles  in  a  blend containing  sulfonated  poly  (2,6-dimethyl-1,4-phenylene  oxide)  and sulfonated polyvinylchloride  via  a  simple  one-step  chemical method.  As-synthesized  nanocomposite  membranes were characterized  using  Fourier  transform  infrared  spectroscopy, scan...

The miscibility of carboxymethyl chitosan/polyethylenimine (CMCS/PEI) blends was analyzed by FT-IR, TGA and SEM. Defect-free CMCS/PEI blend membranes were prepared with polysulfone (PSf) ultrafiltration membranes as support layer for the separation of CO(2)/N(2) mixtures. The results demonstrate that the CMCS/PEI blend is miscible, due to the hydrogen bonding interaction between the two targete...

0014-3057/$ see front matter 2010 Published b doi:10.1016/j.eurpolymj.2010.03.005 * Corresponding author. Tel.: +82 2 958 5299; fax E-mail address: [email protected] (H.-J. Kim). Polymer blending is used to modify or improve the dimensional and thermal stability of any two different polymers or copolymers. In this study, both sulfonated polybenzimidazole homopolymer (MS-p-PBI 100) and sulfonat...

Macromolecular modification of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF) was done with various proportions of sulfonic acid terminated, hyperbranched polysulfone (HPSU) with a view to prepare ion conducting membranes. The PVDF-co-HFP was first chemically modified by dehydrofluorination and chlorosulfonation in order to make the membrane more hydrophilic as well as to introduce uns...

Random-type anion-exchange membranes (AEMs) have been prepared by blending poly(vinyl alcohol) (PVA) and the random copolymer-type polycation, poly(vinyl alcohol-co-methacryloyl aminopropyl trimethyl ammonium chloride) at various molar percentages of anion-exchange groups to vinyl alcohol groups, Cpc, and by cross-linking the PVA chains with glutaraldehyde (GA) solution at various GA concentrat...

a  new  type  of  cation-exchange  nanocomposite  membranes  was prepared  by  in-situ  formation  of  zno  nanoparticles  in  a  blend containing  sulfonated  poly  (2,6-dimethyl-1,4-phenylene  oxide)  and sulfonated polyvinylchloride  via  a  simple  one-step  chemical method.  as-synthesized  nanocomposite  membranes were characterized  using  fourier  transform  infrared  spectroscopy, scan...