In the centrosymmetric binuclear title complex, [Hg(2)Cl(4)(C(12)H(10)N(6))(2)], the Hg(II) ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intra-molecular N-H⋯N hydrogen bond. In the crystal, the binuclear units are connected by inter-molecular N-H⋯Cl hydrogen bonds, as well as π-π stacking inter-actions [ce...

Though vanadium complexes mimic the action of insulin, owing to their toxicity, research is still in progress for a new vanadium complex with maximum efficacy at low concentration and without any side effects. A novel macrocyclic binuclear oxovanadium complex was synthesized, its composition and structure were confirmed by spectral studies and its efficacy was studied in streptozotocin-induced ...

A binuclear lanthanide complex consisting of two lanthanide binding domains linked by a m-xylyl bridging unit forms very stable 1 : 1 adducts with benzene dicarboxylic acids and their derivatives. The complex with isophthalate derivatives is particularly stable.

A new terbium(III) complex with a (3,4-diphenyl)(2-methylthienyl)cyclopentadienyl ligand was synthesized. Single-crystal X-ray analysis revealed binuclear biscyclopentadienyl [TbCl2K]2 core. Luminescence properties of the terbium were analyzed.

A guanidinato-stabilized binuclear yttrium carbyne complex [(PhCH 2 ) NC(NC 6 H 3 i Pr -2,6) ] Y (µ -Me)(AlMe 4 -CH) ( 1 was synthesized via C−H bond activation and its versatile reactivities were investigated. Complex underwent σ-bond metathesis with PhSSPh nucleophilic addition...

Covalently linking two single strand DNA cleaving agents resulted in a new biomimetic binuclear iron complex capable of effecting oxidative double strand DNA cleavage.

Expansion of a Schiff-base polypyrrolic macrocycle allows the formation of a binuclear uranyl complex with co-linear uranyl ions and a very short oxo-oxo distance.

New macrocyclic binuclear nickel(ii) complexes have been synthesized by using the bicompartmental mononuclear complex [NiL] [3,30-((1E,7E)-3,6-dioxa-2,7-diazaocta-1,7-diene-1,8-diyl)bis(3-formyl-5-methyl-2-diolato)nickel(II)] with various diamines like 1,2-bis(aminooxy)ethane (L(1)), 1,2-diamino ethane (L(2)), 1,3-diamino propane (L(3)), 1,4-diamino butane (L(4)), 1,2-diamino benzene (L(5)), an...

In the title binuclear complex, [Fe(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], the Fe(II) ion is six-coordinated by three carboxylate O atoms from three 4-methyl-benzoate ligands, two N atoms from two 1,10-phenanthroline ligands and one bridging aqua ligand in a distorted octa-hedral geometry. The coordinated water mol-ecule acting as the bridging ligand is located on a twofold axes and the...

Binuclear Copper(II) Complex, Super-Exchange Interactions, Antiferromagnetic Coupling Preparation, crystal structure and magnetic properties of a 3,5-dimethylpyrazolate bridged binuclear copper(II) complex [Cu2(L')(3,5 prz)] (L1 = l,3-Bis(2-hydroxy-l-napthylideneamino)propan-2-ol) (1) are reported. Variable-temperature magnetic susceptibility measure­ ments for a powdered sample of the complex ...