In this study, NRTL and UNIQUAC thermodynamic models were used to predict the composition of ternary mixtures of solvents+ m/o/p-cresol+ water in organic and aqueous phases. Various solvents are used for the separation of cresols from water. In this study, methyl propyl ketone, methyl isopropyl ketone, methyl butyl ketone, and methyl isobutyl ketone solvents were investigated. Intermolecular in...

( ) A group-contribution GC method was coupled with the perturbed-hard-sphere-chain ( ) ( ) PHSC equation of state EOS to predict its characteristic parameters. This model can describe both equilibrium and ®olumetric properties of regular fluids and chain-like molecules. The estimation of group contributions for the characteristic ®olume, surface area, and interaction energy was based only on ®...

A method based on the Genetic Algorithm (GA) was developed to study the phase behavior of multicomponent and multiphase systems. Upon application of the GA to the thermodynamic models which are commonly used to study the VLE, VLLE and LLE phase equilibria, the physically meaningful values for the Binary Interaction Parameters (BIP) of the models were obtained. Using the method proposed in t...

The microscopic effect of the exchange interaction parameter for the 2-Dimensional ising model with nearest neighbor interaction has been studied. By supposing simple temperature dependent relationship for the exchange parameter, graphs were straightforwardly obtained that show the reentrant closed looped phase diagrams symptomatic of some colloids and complex fluids and some binary liquids mix...

We have used Monte Carlo simulation and the Gibbs–Duhem integration technique to calculate temperature– composition and pressure–temperature phase diagrams for binary Lennard–Jones mixtures. We systematically explore Lennard–Jones parameter space to demonstrate how the features of these phase diagrams change as a function of diameter ratio, well-depth ratio, binary interaction parameter, and pr...

Predictions of the transport properties self-diffusion coefficient and shear viscosity are presented for a recently developed molecular ammonia model. These data show mean unsigned deviations to the experiment over a temperature range from 200 to 500 K of 8 % for the self-diffusion coefficient and 12% for the shear viscosity. Furthermore, the vapor-liquid equilibria of the ternary system carbon...

Off-line e-cash systems are the digital analogue of regular cash. One of the main desirable properties is anonymity: spending a coin should not reveal the identity of the spender and, at the same time, users should not be able to double-spend coins without being detected. Compact e-cash systems make it possible to store a wallet of O(2) coins using O(L+ λ) bits, where λ is the security paramete...

We perform a comparison of the performance and efficiency of four different function evaluation methods: black-box functions, binary trees, n-ary trees and string parsing. The test consists in evaluating 8 different functions of two variables x, y over 5000 floating point values of the pair (x, y). The outcome of the test indicates that the n-ary tree representation of algebraic expressions is ...

Binarization of grammars is crucial for improving the complexity and performance of parsing and translation. We present a versatile binarization algorithm that can be tailored to a number of grammar formalisms by simply varying a formal parameter. We apply our algorithm to binarizing tree-to-string transducers used in syntax-based machine translation.