This study compared the efficacy of a common medication diluent, bacteriostatic 0.9% sodium chloride containing the preservative benzyl alcohol with lidocaine hydrochloride 1% as an intradermal pretreatment for the relief of pain associated with intravenous cannulation. Forty adult presurgical patients requiring two large bore intravenous catheters were used. They served as their own controls. ...

In this work, benzyl alcohol was obtained in 96% excellent yield by hydrolysis of benzyl chloride catalyzedby the recyclable temperature-dependant phase-separation system that comprised the ionic liquid PEG1000-DAIL[BF4], toluene and ferric sulfate under homogeneous catalysis in aqueous media. This novel methodnot only enhanced the yield, but also made the operating units easy workup. The catal...

Nickel-catalyzed intermolecular benzylation and heterobenzylation of unactivated alkenes to provide functionalized allylbenzene derivatives are described. A wide range of both the benzyl chloride and alkene coupling partners are tolerated. In contrast to analogous palladium-catalyzed variants of this process, all reactions described herein employ electronically unbiased aliphatic olefins (inclu...

Dibenzyl ethers and benzyl chloride can be obtained in moderate to excellent yields through Pd-catalysed reactions in hydrophobic ionic liquids using microwave or conventional heating.

BiFeO3 (BFO), Bi0.86Sm0.07Eu0.07FeO3 (BSEFO), and Bi0.86Sm0.07Cd0.07FeO3 (BSCFO) nano powders were prepared by the sol-gel combustion method and the catalytic performances were evaluated in the acetylation reaction of benzyl alcohol. The physical chemical properties of the catalysts were character...

The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(3)Cl(C(13)H(12)OS)], is situated within a distorted C(3)ClO trigonal-bipyramidal coordination geometry with a mean Sn-C distance of 2.136 (6) Å and with an Sn-O distance of 2.393 (4) Å. The Sn(IV) atom lies 0.171 (3) Å out of the equatorial C(3) plane in the direction of the axially bound Cl atom.

A new ketone Isonitroso phenyl 2 propanone (HINP2P) has been synthesized by the reaction of Benzyl magnesium chloride with cadmium chloride and acetyl chloride. On subsequent treatment of Phenyl 2 propanone with namyl nitrite gives Isonitroso Phenyl 2 Propanone. The structure of these compounds has been confirmed by physiochemical and spectral data. A preliminary screening of these compounds fo...

The pseudo-four component click synthesis of dibenzylated 1,2,3-triazoles derived from aniline is reported. The cycloaddition of sodium azide to N-(prop-2-ynyl)-benzenamine (I) in the presence of equimolar amounts of p-substituted benzyl derivatives, yields a mixture of mono- and dibenzylated 1,2,3-triazoles. When two equivalents of the benzyl derivative are added to the multicomponent reaction...

BiFeO3 (BFO), Bi0.86Sm0.07Eu0.07FeO3 (BSEFO), and Bi0.86Sm0.07Cd0.07FeO3 (BSCFO) nano powders were prepared by the sol-gel combustion method and the catalytic performances were evaluated in the acetylation reaction of benzyl alcohol. The physical chemical properties of the catalysts were character...