A novel and redox-active nanocatalyst, Au(III)-promoted polyaniline gold nanosphere (GPANG), was designed as the nanolabel for highly efficient electrochemical immunoassay of human IgG by coupling with electrocatalytic recycling of self-produced reactants.

Two thermoresponsive polymers based on alkyl modified poly-vinylpyrrolidone (PVP) that exhibit very sensitive and reversible temperature-dependant water solubility are described. The application of these polymers as Au nanocatalyst stabilizers leads to a "smart" thermoresponsive Au nanoparticle catalyst.

Platinum-cerium oxide hybrid nanocatalysts (CeO(2)-Pt) were for the first time designed as bionanolabels for highly efficient electrochemical immunosensing of low-abundance proteins coupling nanocatalyst-based redox cycling with in situ signal amplification strategy.

Immobilizing of zero-valent iron in mono- and bi-metallic systems on the bentonite clay surface as new nanocatalyst were synthesized and used to degrade model acidic dyes from aqueous media. The Fourier-transform infrared spectroscopy, scanning electron microscopy-energy dispersive X-ray spectroscopy, transmission electron microscopy, X-ray diffraction, and Brunauer-Emmett-Teller analysis were ...

Recently, mesoporous carbon nitride (MCN) has aroused extensive interest for its potential applications in organocatalysis, photo- and electrochemistry and CO2 capture. However, further surface functionalization of MCN for advanced nanomaterials and catalysis still remains very challenging. Here we show that acidic carboxyl groups can be smoothly introduced onto the surface of well-ordered MCN ...

In this research, degradation of methylene blue as a dye pollutant was investigated in the presence of TiO2 nanopowders using photolysis and sonolysis systems separately and simultaneously. Effect of different parameters such as catalyst dosage, initial concentration of dye, UV power, pH and type of catalyst on the removal efficiency was ascertained. The results showed that basic pH is proper f...

Self-assembled solution micelles prepared from polystyrene-b-poly(4-vinylpyridine) (PS-b-P4VP) and polystyrene-b-poly(2-vinylpyridine) (PS-b-P2VP), have been employed as templates to synthesize copper nanocatalysts which are regarded as an excellent catalyst system for 1D nanomaterial synthesis. We have demonstrated that uniform-sized nanoparticles with diameters ranging from 1 to 15 nm have be...

Capping agents (organic ligands, polymers, surfactants, etc.) are a basic component in the synthesis of metal nanoparticles with controlled size and well-defined shape. However, their influence on the performances of nanoparticle-based catalysts is multifaceted and controversial. Indeed, capping agent can act as a “poison”, limiting the accessibility of active sites, as well as a “promoter”, pr...

A thermosensitive nanocatalyst was prepared in the reaction of water-soluble iron(III) porphyrins and thermosensitive polymeric nanospheres with a core-shell structure; its catalytic activity in cyclohexene oxidation by iodosylbenzene was dependent markedly on reaction temperatures in aqueous solution.

A strategy for the electrochemical detection of DNA based on catalytic hairpin assembly combined with nanocatalyst label-based redox cycling reaction signal amplification. A superior detection limit of 0.3 aM toward DNA can be achieved.