The effects of different concentrations of CdCl2 and AlCl3 on NH4+ and NO2? oxidation in an aqueous system were investigated. AlCl3 had no effect on NH4+ removal and its oxidation to NO2?, whereas NO2? disappearance was greatly enhanced by AlCl3. In contrast, CdCl2 delayed removal of NH4+ and its subsequent oxidation to NO2? and also decreased the rate of NO2? disappearance. When compared to th...

Put the peroxodisulfate ion (S2O82-) in the phase transfer catalyst banzyltriphenylphosphonium can make a catalyst with mild oxidation property, and used it for oxidation of Benzylhalides to corresponding Benzylaldehyde Compounds. For making catalyst used xylene and water as solvent, and it was an easy process with high yield. Oxidation used in reflux condition with acetonitrile as solvent. The...

background: oxidative modification of low-density lipoprotein (ldl) appears to be an early step in the pathogenesis of atherosclerosis. meanwhile, myeloperoxidase (mpo)-catalyzed reaction is one of the potent pathway for ldl oxidation in vivo. the aim of this study was to evaluate in vitro antioxidant effects of vitamins c and e on ldl oxidation mediated by mpo. methods: mpo was isolated from f...

a novel chemically modified electrode containing prussian blue complex was achieved on the surface of glass carbon electrode by sol-gel technique. the electrochemical behavior of modified electrode was characterized by cyclic voltammetry in detail. the film electrode obtained was very stable and exhibited electrocatalytic response for oxidation of nitrite. results showed at bare gc electrode, a...

coenzyme q10, a lipid soluble benzoquinone, has excellent antioxidant and membrane stabilizing properties in the cardiac tissue. the present study investigated the effects of coenzyme q10 on in vitro ldl oxidation quantitavely. the formation of conjugated dienes, malondialdehyde (mda) and electrophoretic mobility were monitored as markers of the oxidation of ldl, respectively. coenzyme q₁₀ show...

treatment of 10-bromoanthralin (1) with several thiophenols (2) gave the corresponding 10-arylthioanthralins (3) in high yields. oxidation of thioanthralins (3a-c) and (3k-m) using an excess of m-chloroperbenzoic acid gave the corresponding sulfones (4a-c) and (4k-m) in good yields. oxidation of thioanthralins (3d-f) gave a mixture of the corresponding sulfones (4d-f) and anthralin-10,10'-dehyd...

oxidation of low-density lipoprotein (ldl) has been strongly suggested as a key factor in the pathogenesis of atherosclerosis. thus, the inclusion of some anti-oxidant compounds in daily dietary food stuff may inhibit the production of oxidized ldl and may decrease both the development and the progression of atherosclerosis. the present work investigated the inhibitory effects of extract of all...

In order to improve the oxidation resistance of ferritic stainless steel, it is possible to deposit a protective coating on steel substrate. In this research through the usage of pack cementation method a coating of titanium was applied on the surface of AISI 430 stainless steel. Scanning Electron-Microscopy (SEM), Energy- Dispersive X-ray spectrometry (EDAX) and X-ray diffraction (XRD) were us...

vanadium supported on highly ordered nanoporous silica (vox-lus-1) was synthesized and characterized by xrd, nitrogen adsorption‑desorption isotherms and uv-visible spectrophotometer. direct oxidation of benzene to phenol in liquid phase by h2o2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). the maximum yield (25%) and selectivity (73%) of the ph...