Density functional theory (DFT) has been applied to model the structure of (Ag•CH2OH/A) complexes previously experimentally characterized by electron paramagnetic resonance (EPR) in zeolite matrices. The magnetic parameters of (Ag•CH2OH/A) were found to depend on the local structure of the zeolite represented by clusters referred to as 3T and 6T, and also on the applied computational method. A ...

Electrospray ionization tandem mass spectrometry (ESI-MS/MS) was used to probe the binding of silver ions and reduced silver species with polyamidoamine generation 1 amine-terminated (PAMAMG1NH2) and generation 2 hydroxyl-terminated (PAMAMG2OH) dendrimers. At Ag(+)/PAMAMG2OH molar ratios of 1, 2:1 and low abundance 3:1 complexes emerge. Similar...

The effect of different sizes of structure directing agents on the ordering of the fluoride ions in pure silica MFI zeolites has been determined using magic angle spinning solid state NMR. By synthesizing fluoride containing pure silica MFI zeolites using methyltributylammonium cations as the structure directing agent, it has been possible to change the type of ordering seen for the fluoride io...

Background: Wound healing is a complicated process involving the proliferation of the epithelial cells, deposition of granulation tissue as well as recruitment of inflammatory cells. It also is a hot topic of research for trauma, orthopedics and general surgery studies. There are many forms of cells involved in this process. This study aimed to design a tissue-engineered wound dressing consisti...

Zeolites are nanoporous crystalline alumino-silicates with a rich variety of interesting properties and industrial applications. With over 140 zeolite framework topologies synthetically available—each with its own range of compositions—zeolites offer size-, shapeand electrostaticallyselective adsorption, diffusion and reaction up to remarkably high temperatures. Zeolites are widely used as petr...

Surface bio-contamination is a problem that contributes to outbreaks of community-acquired and nosocomial infection through episodic fomite transmission of disease and through persistent fomitic reservoirs. The extent to which fomitic reservoirs contribute to the overall extent of nosocomial infection is unknown, but fomites are known to play some role in the transmission of many diseases, incl...

Silver ion has been used for centuries to prevent and treat a variety of diseases and infections. In recent years, extensive studies have been undertaken on the use of antimicrobial properties of silver, incorporated within medical devices. The aim of this study was to prepare a formulation containing silver ion, which could be applied for wound dressing. The purity of nanosilver was measured b...

Zeolites have potential application as ion-exchangers, catalysts and molecular sieves. Zeolites are once again drawing attention in Japan as stable adsorbents and solidification materials of fission products, such as (137)Cs(+) from damaged nuclear-power plants. Although there is a long history of scientific studies on the crystal structures and ion-exchange properties of zeolites for practical...