نتایج جستجو برای: azlactone

تعداد نتایج: 58  

Journal: :Journal of materials chemistry 2011
Eric M Saurer Ryan M Flessner Maren E Buck David M Lynn

We report on the fabrication of covalently crosslinked and amine-reactive hollow microcapsules using 'reactive' layer-by-layer assembly to deposit thin polymer films on sacrificial microparticle templates. Our approach is based on the alternating deposition of layers of a synthetic polyamine and a polymer containing reactive azlactone functionality. Multilayered films composed of branched poly(...

Journal: :Journal of the American Chemical Society 2011
Asa D Melhado Giovanni W Amarante Z Jane Wang Marco Luparia F Dean Toste

Azlactones participate in stereoselective reactions with electron-deficient alkenes and N-sulfonyl aldimines to give products of 1,3-dipolar cycloaddition and Mannich addition reactions, respectively. Both of these reactions proceed with good to excellent diastereo- and enantioselectivity using a single class of gold catalysts, namely C(2)-symmetric bis(phosphinegold(I) carboxylate) complexes. ...

2013
Hanne Kolsrud Hustoft Ole Kristian Brandtzaeg Magnus Rogeberg Dorna Misaghian Silje Bøen Torsetnes Tyge Greibrokk Léon Reubsaet Steven Ray Wilson Elsa Lundanes

Reliable, sensitive and automatable analytical methodology is of great value in e.g. cancer diagnostics. In this context, an on-line system for enzymatic cleavage of proteins, subsequent peptide separation by liquid chromatography (LC) with mass spectrometric detection has been developed using "sub-chip" columns (10-20 μm inner diameter, ID). The system could detect attomole amounts of isolated...

Journal: :Journal of polymer science 2021

Polymer coatings are frequently used to modify surface properties of inorganic substrates. However, the disparity in physical between polymer film and substrate often leads residual stress development, which can be deleterious overall performance coated materials. This work reports molecular design films that dissipate upon irradiation with ultraviolet (UV) light. These polymers synthesized by ...

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