A cascade signal amplification strategy was proposed for detection of cancer cells at ultralow concentration by combining the rolling circle amplification (RCA) technique with oligonucleotide functionalized nanoparticles (NPs), and anodic stripping voltammetric detection. This flexible biosensing system exhibited high sensitivity and specificity with the detection limits of 10 Ramos cells mL(-1).

Electrochemistry combined on-line with inductively coupled plasma-atomic emission spectrometry (EC/ICP-AES) was used to study the electrode reactions of rabbit liver metallothionein (MT) adsorbates at thin mercury films (TMFs). Three major oxidation peaks, with peak potentials at −1.20, −0.75 and −0.32 V, were observed. Through the correlation of the DPV characteristics to the elution of the Zn...

Using a paraffin impregnated graphite electrode (PIGE) and mercury-modifiedpyrolytic graphite electrode with basal orientation (Hg-PGEb) copper(II) and Cu(II)-DNApurine base solutions have been studied by cyclic (CV) and linear sweep voltammetry(LSV) in connection with elimination voltammetry with linear scan (EVLS). In chlorideand bromide solutions (pH 6), the redox process of Cu(II) proceeded...

An automatic system for the determination of Zn, Cd, Pb and Cu by anodic stripping potentiometry using the oxygen dissolved in the sample as oxidant is reported. The system relies on the use of a PC-compatible computer for instrumental control and data acquisition and processing.

Nitrogen doped diamond-like carbon (N-DLC) thin films were prepared on n-Si substrates using a filtered cathodic vacuum arc deposition method. Square wave anodic stripping voltammetry (SWASV) was used to trace Pb and Cu in a neutral KCl solution with pH 7. Stripping voltammograms of Pb and Cu were analyzed in terms of metal concentration, deposition time and deposition potential. The SWASV resu...

An electrochemical anodic stripping procedure for ultra-trace assay of xanthine in Cu2þ solution at a glassy carbon electrode (GCE) is described. Cyclic voltammetry was used to characterize the nature of the process taking place at the GCE. The anodic stripping response in the presence of Cu2þ, at 150 mV (peak I) and 600 mV (peak II), is evaluated with respect to various experimental and instru...

We have examined the anodic stripping voltammetry (ASV) of Cd and Pb at carbon screen printed electrodes modified by an in situ deposited Bi film, and have demonstrated significant cross talk between the stripping peaks of the two metals. A simple and generally applicable method for dealing with this problem is described, based on curve-fitting three-dimensional calibration plots using MATLAB. ...

Trace uranium detection measurement was performed using DNA immobilized on a graphite pencil electrode (DGE). The developed probe was connected to the portable handheld voltammetric systems used for seawater analysis. The sensitive voltammogram was obtained within only 30 s accumulation time, and the anodic stripping working range was attained at 100~800 μg/l U and 10~50 μg/l. The statistic rel...

Ultrasonically-enhanced mass transport was exploited to increase preconcentration efficiency in anodic stripping voltammetry. We developed a Nafion-coated mercury thin-film working electrode which is stable under ultrasonic irradiation, making it possible to achieve very low limits of detection for relatively short preconcentration times. This allows the investigation of a variety of biological...