The thermal crystallization of citrate-stabilized amorphous calcium phosphate leads to the formation pure hydroxyapatite and represents an interesting route for producing ceramics biomedical applications.

Human dental enamel, the hardest tissue in the body, plays a vital role in protecting teeth from wear as a result of daily grinding and chewing as well as from chemical attack. It is well established that the mechanical strength and fatigue resistance of dental enamel are derived from its hierarchical structure, which consists of periodically arranged bundles of hydroxyapatite (HAP) nanowires. ...

A simple synthetic method is presented for the precipitation of high purity, dry amorphous calcium carbonate (ACC) based on freeze-drying saturated, counter ion free CaCO3 solutions, where the ACC produced shows an extended atmospheric stability. Translation of the methodology to amorphous calcium phosphate demonstrates the generality of the approach.

background: some studies have shown that casein phosphopeptide-amorphous calcium phosphate (cpp-acp) and acidulated phosphate fluoride (apf) gel can protect teeth against erosion. the aim of this study was to assess whether cpp-acp and fluoride could reduce enamel wear rates under erosive conditions simulating abrasion and acidic diet regimen. materials and methods: enamel specimens consisted o...

EXAFS can be used to characterise the phase of an amorphous calcified deposit mixed with a crystalline phase which does not contain calcium. In such a mixture, the amorphous phase may not be detectable by X-ray diffraction. This application of EXAFS is illustrated by the characterisation of the calcium phosphate deposited in association with struvite in encrusted urinary catheters.

BACKGROUND Researchers are looking for biomimetic mineralization of ena/mel to manage dental erosion. This study evaluated biomimetic mineralization of demineralized enamel induced by a synthetic and self-assembled oligopeptide amphiphile (OPA). RESULTS The results showed that the OPA self-assembled into nano-fibres in the presence of calcium ions and in neutral acidity. The OPA was alternate...

A simple route for synthesizing nano-sized beta-tricalcium phosphate (beta-TCP) at room temperature has been developed in methanol solvent. The phase evolution from CaHPO4, intermediate amorphous calcium phosphate (ACP) phases (including ACP1 and ACP2 with different structures) to final beta-TCP with increasing aging time was observed. The formation of beta-TCP phase is favored due to the incor...

Casein phosphopeptides-amorphous calcium phosphate (CPP-ACP) is a bioactive agent with a base of milk products, which has been formulated from two parts: casein phosphopeptides (CPP) and amorphous calcium phosphate (ACP). CPP was produced from milk protein casein and has a remarkable ability to stabilize calcium phosphate in solution and to substantially increase the level of calcium phosphate ...

Infrared internal reflection spectroscopy (IRS) was used to investigate chemical changes of enamel surface during in vitro remineralization. Specimens were demineralized and exposed either to calcium phosphate-fluoride solutions or to acidulated fluorophosphate. The former showed amorphous phosphate remineralization, and the latter showed surface precipitate interpreted to be calcium fluoride. ...

Crustaceans, like most mineralized invertebrates, adopted calcium carbonate mineralization for bulk skeleton reinforcement. Here, we show that a major part of the crustacean class Malacostraca (which includes lobsters, crayfishes, prawns and shrimps) shifted toward the formation of calcium phosphate as the main mineral at specified locations of the mandibular teeth. In these structures, calcium...