The structure of the title salt, (C(6)H(14)N)(2)[CuBr(4)], is built up from cyclo-hexyl-ammonium cations and tetra-bromidocuprate anions, the latter being located on an inversion center. In the crystal, anions and cations are inter-connected by N-H⋯Br hydrogen bonds, forming ribbons parallel to [0-11].

Alcaligenes faecalis No. 4 (No. 4), which conducts heterotrophic nitrification and aerobic denitrification, removed 800 mg-N/l of highstrength ammonium and 100 mg-P/l of phosphorus, both in a synthetic medium and in an anaerobically digested municipal sludge solution. The estimated N2 conversion ratio from ammonium-nitrogen was approximately 50%. When the initial phosphorus concentration was re...

In situ Raman spectra of chemisorbed azobenzene (AB) monolayers on glassy carbon (GC) electrodes were observed under potentiostatic conditions in acetonitrile (ACN) with tetrabutyl-ammonium tetrafluoroborate (TBA-BF4). The Raman intensities of these spectra were high below -1000 mV, and this is attributed to the change in absorbance of AB on GC. In this paper, we describe chemisorbed AB molecul...

A series of backbone modified and sulfonic acid replacement analogs of our topical, clinical candidate (iii) were synthesized. Their antimicrobial activities and aqueous stabilities at pH 4 and pH 7 were determined, and has led us to identify quaternary ammonium N,N-dichloroamines as a new class of topical antimicrobial agents.

The unique high-resolution feature offered by 14N magic-angle spinning (MAS) NMR spectroscopy of ammonium ions has been used to characterize the crystal structures of various ammonium molybdates by their 14N quadrupole coupling parameters, i.e., CQ, the quadrupole coupling constant, and etaQ, the asymmetry parameter. Two polymorphs of diammonium monomolybdate, (NH4)2MoO4, recently structurally ...

In the structure of the title compound, NH(4) (+)·C(8)H(11)O(4) (-), the carboxyl and carboxyl-ate groups of the cation adopt C-C-C-O torsion angles of 174.9 (2) and -145.4 (2)°, respectively, with the alicyclic ring. The ammonium H atoms of the cations give a total of five hydrogen-bonding associations with carboxyl-ate O-atom acceptors of the anion which, together with a carboxyl O-H⋯O(carbox...

Phase transitions and hygroscopic growth of aerosol particles containing humic acid and mixtures of humic acid and ammonium sulphate C. L. Badger, I. George, P. T. Griffiths, C. F. Braban, R. A. Cox, and J. P. D. Abbatt Centre for Atmospheric Science, Dept. of Chemistry, Lensfield Road, University of Cambridge, Cambridge, CB2 1EW, UK Department of Chemistry, University of Toronto, ON, M5S 3H6, ...

The factors affecting the copper-catalyzed rearrangement of ammonium ylids derived from tetrahydropyridines and diazoesters have been examined,and the first examples of high-yielding metal-catalyzed [2,3]-sigmatropic rearrangements of a wide range of such ylids are reported. The nature of the alpha-substituent in the diazo component of the reaction has a dramatic effect upon the yields of the r...

In the crystal structure of the title salt, NH(4) (+).[(C(6)H(5))P(O)(2)(OH)](-) or NH(4) (+)·C(6)H(6)O(3)P(-), the N and O atoms inter-act via hydrogen bonds to generate a layer motif. The phenyl rings are stacked above and below this layer, sandwiching the hydrogen-bonded layer.

The title salt, C(4)H(10)Br(2)N(+)·Br(-), crystallizes with four cations and four anions in the asymmetric unit. In the crystal, the bis-(2-bromo-eth-yl)ammonium cations and bromide anions are linked into chains by N-H⋯Br hydrogen bonds describing a binary C(2) (1)(4) motif along [010]. Each of these chains is formed by a unique cation and anion pair. The ammonium cations occur in the less pref...