in present research work, homogeneous anion exchange membranes based on polysulfone (qapsfs) were prepared via chloromethylation, amination and alkalization. in amination step, trimethylamine and n,n,n',n'-tetramethyl-1,6-hexanediamine were used as amination and crosslinking agents, respectively. the chloromethylated polysulfone was characterized by 1hnmr spectroscopy and chloromethylation degr...

This paper reports on a single alkaline exchange membrane direct formate fuel cell (AEM DFFC) consisting of a carbon-supported palladium catalyst at the anode, a quaternized polysulfone membrane, and a non-precious Fe–Co catalyst at the cathode. It is demonstrated that the AEM DFFC yields a peak power density of 130 mW cm 2 with 5 M potassium formate (HCOOK) at 80 C. It is further shown that wi...

In this paper, raspberry hollow Pd nanospheres (HPNs)-decorated carbon nanotube (CNT) was developed for electro-oxidation of methanol, ethanol, and formic acid in alkaline media. The electrocatalyst was fabricated simply by attaching HPNs onto the surface of CNT which had been functionalized by polymer wrapping. The as-prepared HPN-CNTs (CHPNs) were characterized by transmission electron micros...

Palladium-nickel (PdNi) hollow nanoparticles were synthesized via a modified galvanic replacement method using Ni nanoparticles as sacrificial templates in an aqueous medium. X-ray diffraction and transmission electron microscopy show that the as-synthesized nanoparticles are alloyed nanostructures and have hollow interiors with an average particle size of 30 nm and shell thickness of 5 nm. Com...

to simulate a new economical architecture for pem fuel cell and investigate the effectiveness of the introduced structure on the performance, computational fluid dynamics (cfd) code is used to solve the equations for a single domain of the cell namely: the flow field, the mass conservation, the energy conservation, the species transport, and the electric/ionic fields under the assumptions of st...

Hydrogen, presently, finds application as a chemical rather than a fuel in commercial operations. However, being a non-polluting source of energy, hydrogen is predicted to be the ‘‘fuel of the future’’. One of the most potential applications for hydrogen is to power fuel cells. Major automobile manufacturers are currently working towards developing fuel cell vehicles; such vehicles are expected...

Improving cell performance and durability through both new materials and membrane electrode processing optimization is needed for the commercialization of alkaline membrane fuel cell (AMFC) technologies. In this work, we adopted an in-situ cross-linking strategy of an anion-conducting block copolymer to prepare durable ionomers for use in alkaline membrane fuel cells (AMFCs). Our goal was to us...

Hybrid polymer electrolyte fuel cells combine a proton exchange membrane PEM and anion exchange membrane AEM and exhibit unique advantages. The electrochemical performance and current limitations of a hybrid cell with an alkaline electrode fabricated on a Nafion membrane was characterized at 70°C as a function of relative humidity. To separate the individual characteristics of the AEM anode and...